Abstract:
Diaziridine molecules in the title complexes 1 and 2, respectively, are bidentate ligands and form coordination polymers in which silver ions are coordinated to the trans-oriented nitrogen lone pairs of the ligands; complex 1 is homochiral (space group P212121), whereas 2 is a pseudoracemate (space group Pbca) in which the alternation of ligands with opposite configurations is statistically disordered.
Document Type:
Article
Language: English
Citation:
R. G. Kostyanovsky, K. A. Lyssenko, V. R. Kostyanovsky, “Homochiral and pseudoracemic 3,3- and 1,2-dimethyldiaziridine–silver nitrate complexes”, Mendeleev Commun., 10:2 (2000), 44–46
Linking options:
https://www.mathnet.ru/eng/mendc4374
https://www.mathnet.ru/eng/mendc/v10/i2/p44
This publication is cited in the following 9 articles:
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Yu. S. Syroeshkina, L. L. Fershtat, M. A. Syroeshkin, V. V. Kuznetsov, K. A. Lyssenko, N. N. Makhova, “First synthesis of 1,5-diazabicyclo[3.1.0]hexane complexes with cadmium salts”, Russ Chem Bull, 58:5 (2009), 1002
G.D. McAllister, A. Perry, R.J.K. Taylor, Comprehensive Heterocyclic Chemistry III, 2008, 539
T. V. Skrupskaya, A. A. Kislukhin, A. V. Shevtsov, V. Yu. Petukhova, K. A. Lyssenko, N. N. Makhova, “Complexes of αω-bis(3,3-dialkyldiaziridin-1-yl)alkanes and their bis(2-arylcarbamoyl) derivatives with cadmium and nickel salts”, Russ Chem Bull, 57:1 (2008), 56
Qiong Ye, Xi-Sen Wang, Hong Zhao, Ren-Gen Xiong, “Spontaneous resolution of a novel chiral coordination polymer through supramolecular interactions and solvent symmetry breaking”, Tetrahedron: Asymmetry, 16:9 (2005), 1595
R. G. Kostyanovsky, V. R. Kostyanovsky, G. K. Kadorkina, K. A. Lyssenko, “Asymmetric three-coordinated nitrogen compounds: spontaneous resolution and absolute asymmetric synthesis”, Mendeleev Commun., 13:3 (2003), 111–113
D. A. Lenev, K. A. Lyssenko, R. G. Kostyanovsky, “Asymmetric nitrogen”, Russ Chem Bull, 49:7 (2000), 1241
R. G. Kostyanovsky, V. R. Kostyanovsky, G. K. Kadorkina, V. Yu. Torbeev, “Resolution of racemates with achiral reagents”, Mendeleev Commun., 10:3 (2000), 83–84
N. N. Makhova, A. N. Mikhailyuk, V. V. Kuznetsov, S. A. Kutepov, P. A. Belyakov, “Effective synthesis of 1,2-di-, 1,2,3-tri-, 1,2,3,3-tetraalkyldiaziridines and 1,5-diazabicyclo[3.1.0]hexanes”, Mendeleev Commun., 10:5 (2000), 182–185
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