Abstract:
Using laser photoemission, we found two routes of the electroreduction of α-radicals (Rads) adsorbed on a mercury electrode for linear and cyclic ethers in the presence of strong proton donors (BH+), i.e., by direct one-electron transfer and with the antecedent formation of the metastable complex [Rads·BH+]
Document Type:
Article
Language: English
Citation:
A. G. Krivenko, A. S. Kotkin, V. A. Kurmaz, “Effect of proton donors on the mechanism of electroreduction of α-radicals of linear and cyclic ethers”, Mendeleev Commun., 10:2 (2000), 46–49
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https://www.mathnet.ru/eng/mendc4375
https://www.mathnet.ru/eng/mendc/v10/i2/p46
This publication is cited in the following 5 articles:
V. A. Kurmaz, V. P. Gul'tyai, “The main trends in the development of electrochemistry of organic compounds in Russia (based on the materials of the 18th All-Russian Conference “EKHOS-2014”)”, Russ J Electrochem, 51:11 (2015), 991
I. F. Sakhapov, Z. N. Gafurov, V. M. Babaev, V. A. Kurmaz, R. R. Mukhametbareev, I. Kh. Rizvanov, O. G. Sinyashin, D. G. Yakhvarov, “Electrochemical properties and reactivity of organonickel sigma-complex [NiBr(Mes)(bpy)] (Mes = 2,4,6-trimethylphenyl, bpy = 2,2′-bipyridine)”, Russ J Electrochem, 51:11 (2015), 1061
A. G. Krivenko, A. S. Kotkin, V. A. Kurmaz, “Thermodynamic and kinetic characteristics of intermediates of electrode reactions: Determination by direct and combined electrochemical methods”, Russ J Electrochem, 41:2 (2005), 122
Alexander G Krivenko, Alexander S Kotkin, Vladimir A Kurmaz, “Mechanism of electroreduction of intermediates with and without a proton donor”, Electrochimica Acta, 47:24 (2002), 3891
A. G. Krivenko, V. A. Kurmaz, A. S. Kotkin, “Prospects for the determination of thermodynamic and kinetic parameters of electrode reaction intermediates by laser photoemission”, Mendeleev Commun., 12:1 (2002), 11–14
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