Аннотация:
A comparative study of N-heterocyclic carbene Pd complexes in the head-to-head isoprene telomerization with methanol revealed significant impact of ligand structure as well as axial group structure on the catalyst activity. Some N,N'-diaryl substituted imidazol-2-ylidene, imidazolidin-2-ylidene and expanded-ring tetrahydropyrimidin-2-ylidene and tetrahydrodiazepin-2-ylidene based ligands were tested to explore the fundamental correlations between structure (ring carbene size along with the substituent sterical and electronic properties) and catalytic activity.
Образец цитирования:
S. A. Rzhevskiy, M. A. Topchiy, V. N. Bogachev, A. A. Ageshina, L. I. Minaeva, G. K. Sterligov, M. S. Nechaev, A. F. Asachenko, “NHC Pdii complexes for the solvent-free telomerisation of isoprene with methanol”, Mendeleev Commun., 31:4 (2021), 478–480
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https://www.mathnet.ru/rus/mendc961
https://www.mathnet.ru/rus/mendc/v31/i4/p478
Эта публикация цитируется в следующих 13 статьяx:
Tongliang Zhou, Greta Utecht-Jarzyńska, Michal Szostak, “Ring-expanded N-heterocyclic carbene (reNHC) complexes: Applications in transition metal catalysis”, Coordination Chemistry Reviews, 512 (2024), 215867
Belén Lerma-Berlanga, José Pedro Cerón-Carrasco, Antonio Leyva-Pérez, “Diverted Telomerization Reaction with Aryl Boronic Derivatives: Expeditious Synthesis of Aryl-Substituted 1,6- and 1,7-dienes”, Organometallics, 43:17 (2024), 1827
Roman O. Pankov, Darya O. Prima, Valentine P. Ananikov, “Tailoring metal complexes with N-heterocyclic carbene ligands using Electron-Withdrawing Groups: Impact on catalytic activity and property development”, Coordination Chemistry Reviews, 516 (2024), 215897
A. A. Beloglazkin, S. A. Rzhevsky, E. A. Drokin, M. A. Topchiy, A. F. Asachenko, R. S. Borisov, E. V. Bermesheva, “Study of the Telomerization Reaction of Isoprene with Methanol Catalyzed by N-Heterocyclic Carbene Pd(II) Complexes Using Mass Spectrometry and NMR Spectrometry”, J Anal Chem, 78:14 (2023), 1879
G. K. Sterligov, A. N. Lysenko, E. A. Drokin, L. I. Minaeva, M. A. Topchiy, A. A. Ageshina, S. A. Rzhevskiy, M. S. Nechaev, A. F. Asachenko, “Solvent-free and transition metal catalyst-free synthesis of indolo[1,2-f]phenanthridine from 6-chlorophenanthridine”, Russ Chem Bull, 71:3 (2022), 479
G. A. Gurina, A. V. Markin, A. V. Cherkasov, A. M. Ob'edkov, A. A. Trifonov, “Synthesis, structure, and properties of the Sc chloride complex coordinated by the tridentate bis(phenolate)-tethered NHC ligand”, Russ Chem Bull, 71:2 (2022), 306
M. M. Efremova, N. V. Rostovskii, “The VIth International Symposium “The Chemistry of Diazo Compounds and Related Systems” (DIAZO 2021)”, Russ J Org Chem, 58:3 (2022), 335
M. A. Topchiy, A. A. Ageshina, S. A. Rzhevskiy, L. I. Minaeva, M. S. Nechaev, A. F. Asachenko, “Solvent-free telomerization of isoprene with alcohols catalyzed by palladium(ɪɪ) carbene complexes”, Russ Chem Bull, 71:5 (2022), 940
Olga V. Shurupova, Sergey A. Rzhevskiy, Lidiya I. Minaeva, Maxim A. Topchiy, Andrey F. Asachenko, “Highly efficient synthesis of 3,4-diarylbutadiene sulfones using Heck–Matsuda reaction”, RSC Adv., 12:9 (2022), 5517
M. A. Topchiy, A. N. Lysenko, M. A. Rasskazova, A. A. Ageshina, S. A. Rzhevskiy, L. I. Minaeva, M. S. Nechaev, A. F. Asachenko, “Arylation of nitromethane with sterically hindered aryl halides”, Russ Chem Bull, 71:1 (2022), 59
O. V. Shurupova, G. K. Sterligov, M. A. Rasskazova, E. A. Drokin, A. N. Lysenko, S. A. Rzhevskiy, L. I. Minaeva, M. A. Topchiy, A. F. Asachenko, “One-pot two step synthesis of unsymmetrically substituted indenes from 3,4-diarylbutadiene sulfones”, Mendeleev Commun., 32:4 (2022), 446–448
S. A. Rzhevskiy, M. A. Topchiy, V. N. Bogachev, L. I. Minaeva, I. R. Cherkashchenko, K. V. Lavrov, G. K. Sterligov, M. S. Nechaev, A. F. Asachenko, “Solvent-free palladium-catalyzed C–O cross-coupling of (hetero)aryl halides with primary alcohols”, Mendeleev Commun., 32:2 (2022), 258–259
V.-H. Nguyen, H. T. Phung, D. T. Doan, T. T. Do, “Highly cytotoxic palladium(ii) complexes with 1,2,4-triazole-derived carbene ligands”, Mendeleev Commun., 32:5 (2022), 594–596
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