Аннотация:
1,2-Dimethyl-3-(3,3-diethoxypropyn-1-yl)-and 1,2-dimethyl-3-(3-hydroxymethyl-3-methylbutyn-1-yl)diaziridines have been synthesised by the interaction of 4,4-diethoxybutyn-2-al and 4-hydroxymethyl-4-methylpentyn-2-al, respectively, with equimolar amounts of MeNH2 and MeNHCl (or MeNHOSO3H) at pH 9.5–10; the use of an excess of an amine in reactions with 4,4-diethoxybutyn-2-al resulted in a mixture of isomeric 5(3)-diethoxymethyl-1-methylpyrazoles and a mixture of Z/E isomers of 1-cyano- 3,3-diethoxy-2-methylaminoprop-1-enes.
Тип публикации:
Статья
Язык публикации: английский
Образец цитирования:
N. N. Makhova, N. G. Kamalova, Yu. A. Strelenko, “Synthesis of the first representatives of 3-ethynyldiaziridines”, Mendeleev Commun., 11:6 (2001), 227–229
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc4308
https://www.mathnet.ru/rus/mendc/v11/i6/p227
Эта публикация цитируется в следующих 3 статьяx:
Karine A. Eliazyan, Frunze V. Avetisyan, Tamara L. Jivanshiryan, Vergush A. Pivazyan, Emma A. Ghazaryan, Lusya V. Shahbazyan, Siranush V. Harutyunyan, Aleksandr P. Yengoyan, “Synthesis and fungicidal activity of novel 1,3‐disubstituted 1H‐diazirine derivatives”, Journal of Heterocyclic Chem, 48:1 (2011), 118
Géza Stájer, Pál Sohár, Antal Csámpai, Reijo Sillanpää, Ferenc Fülöp, “Preparation and Structure of Bicycloalkane-Condensed Aryldiaziridines Accompanied by Pyrimidines”, HETEROCYCLES, 71:6 (2007), 1315
Nina N. Makhova, Nailya G. Kamalova, Yurii A. Strelenko, “ChemInform Abstract: Synthesis of the First Representatives of 3‐Ethynyldiaziridines.”, ChemInform, 33:23 (2002)