Аннотация:
The reaction of cobalt dibromide hexahydrate with 2,2’-bipyridine (bpy) and mesitylphosphinic acid MesP(O)(OH)H (Mes = = 2,4,6-trimethylphenyl) under solvothermal synthesis conditions leads to a new dinuclear cobalt(ii) complex {Co2[µ-O2P(H)Mes]2- (bpy)4}Br2 formed by two bridging {µ-O2P(H)Mes}– ligands. X-ray crystal structure analysis of the complex displayed that cobalt ions have distorted octahedral coordination and are doubly bridged by two mesitylphosphinato ligands.
Образец цитирования:
E. A. Trofimova, A. B. Dobrynin, T. P. Gerasimova, S. A. Katsyuba, O. G. Sinyashin, D. G. Yakhvarov, “Synthesis, X-ray crystal structure and quantum-chemical study of new dinuclear cobalt complex {Co2[mmm-O2P(H)Mes]2(bpy)4}Br2”, Mendeleev Commun., 23:3 (2013), 135–136
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc2638
https://www.mathnet.ru/rus/mendc/v23/i3/p135
Эта публикация цитируется в следующих 6 статьяx:
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N. K. Gusarova, A. O. Sutyrina, V. A. Kuimov, S. F. Malysheva, N. A. Belogorlova, P. A. Volkov, B. A. Trofimov, “Single-stage synthesis of alkyl-H-phosphinic acids from elemental phosphorus and alkyl bromides”, Mendeleev Commun., 29:3 (2019), 328–330
Amanda N. Graveson, Celia M. Gendron-Herndon, Alexander N. Erickson, Carolyn N. Virca, Michael A. Paton, Edward J. Valente, Eugenijus Urnezius, “Discrete bimetallic Co(II) phosphinate complexes supported by 2,6-dimesitylphenylphosphinate ligand”, Polyhedron, 123 (2017), 14
Tatiana P. Gerasimova, Sergey A. Katsyuba, Ludmila G. Lavrenova, Vladimir Pelmenschikov, Martin Kaupp, “Correlations between metal spin states and vibrational spectra of a trinuclear Fe(II) complex exhibiting spin crossover”, Journal of Molecular Structure, 1101 (2015), 8
D. G. Yakhvarov, E. A. Trofimova, A. B. Dobrynin, T. P. Gerasimova, S. A. Katsyuba, O. G. Sinyashin, “First neutral dinuclear cobalt complex formed by bridging [μ-O2P(H)R]– ligands: synthesis, X-ray crystal structure and quantum-chemical study”, Mendeleev Commun., 25:1 (2015), 27–28
I. S. Kovalev, D. S. Kopchuk, A. F. Khasanov, G. V. Zyryanov, V. L. Rusinov, O. N. Chupakhin, “The synthesis of polyarene-modified 5-phenyl-2,2'-bipyridines via the SHN methodology and aza-Diels–Alder reaction”, Mendeleev Commun., 24:2 (2014), 117–118