Аннотация:
Elemental phosphorus (red or white) reacts with alkyl bromides at 60–62°C in the phase-transfer catalytic system KOH/H2O/PhMe/Et3BnNCl to afford alkyl-H-phosphinic acids in up to 47% yield.
Образец цитирования:
N. K. Gusarova, A. O. Sutyrina, V. A. Kuimov, S. F. Malysheva, N. A. Belogorlova, P. A. Volkov, B. A. Trofimov, “Single-stage synthesis of alkyl-H-phosphinic acids from elemental phosphorus and alkyl bromides”, Mendeleev Commun., 29:3 (2019), 328–330
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc1513
https://www.mathnet.ru/rus/mendc/v29/i3/p328
Эта публикация цитируется в следующих 11 статьяx:
Kseniya O. Khrapova, Pavel A. Volkov, Anton A. Telezhkin, Alexander I. Albanov, Oleg N. Chupakhin, Boris A. Trofimov, “Catalyst- and solvent-free regiospecific SNHAr phosphinylation of pyridines with H-phosphinates mediated by benzoylphenylacetylene”, Org. Biomol. Chem., 22:26 (2024), 5419
Vladimir A. Kuimov, Svetlana F. Malysheva, Natalia A. Belogorlova, Ruslan I. Fattakhov, Alexander I. Albanov, Boris A. Trofimov, “Triton-X-100 as an Organic Catalyst for One-Pot Synthesis of Arylmethyl-H-phosphinic Acids from Red Phosphorus and Arylmethyl Halides in the KOH/H2O/Toluene Multiphase Superbase System”, Catalysts, 13:4 (2023), 720
Gaukhar K. Bishimbayeva, Nina K. Gusarova, Arailym M. Nalibayeva, Svetlana I. Verkhoturova, Amangul Bold, Natalya A. Chernysheva, Assem K. Zhangabayeva, Svetlana N. Arbuzova, Yerlan N. Abdikalykov, Dinara S. Zhumabayeva, “Synthesis and Properties of Sulfur-Containing Organophosphorus Extractants Based on Red Phosphorus, Alkyl Bromides, and Elemental Sulfur”, Materials, 16:9 (2023), 3394
S. F. Malysheva, V. A. Kuimov, S. N. Arbuzova, “Elemental Phosphorus in the Synthesis of Organophosphorus Compounds: The Recent Advances (A Review)”, Russ J Gen Chem, 93:S1 (2023), S238
S. F. Malysheva, V. A. Kuimov, N. A. Belogorlova, K. O. Khrapova, K. A. Apartsin, N. K. Gusarova, “Chemoselective Synthesis of Alkylphosphinic Acids from Red Phosphorus and Alkyl Bromides in the System KOH/H2O/Toluene/Micellar Catalyst”, Russ J Org Chem, 58:2 (2022), 192
P. A. Volkov, K. O. Khrapova, A. A. Telezhkin, S. F. Malysheva, L. I. Larina, B. A. Trofimov, “Synthesis of alkyl-H-phosphinic acid alkyl esters from red phosphorus and alkyl bromides”, Mendeleev Commun., 32:6 (2022), 792–794
Vladimir A. Kuimov, Svetlana F. Malysheva, Natalia A. Belogorlova, Alexander I. Albanov, Nina K. Gusarova, Boris A. Trofimov, “Synthesis of Long‐Chain n‐Alkylphosphonic Acids by Phosphonylation of Alkyl Bromides with Red Phosphorus and Superbase under Micellar/Phase Transfer Catalysis”, Eur J Org Chem, 2021:10 (2021), 1596
Vladimir A. Kuimov, Svetlana F. Malysheva, Natalia A. Belogorlova, Nina K. Gusarova, Boris A. Trofimov, “Chemoselective synthesis of long-chain alkyl-H-phosphinic acids via one-pot alkylation/oxidation of red phosphorus with alkyl-PEGs as recyclable micellar catalysts”, Org. Biomol. Chem., 19:48 (2021), 10587
Н. К. Гусарова, Б. А. Трофимов, “Химия фосфорорганических соединений на основе элементного фосфора: достижения и горизонты”, Усп. хим., 89:2 (2020), 225–249; N. K. Gusarova, B. A. Trofimov, “Organophosphorus chemistry based on elemental phosphorus: advances and horizons”, Russian Chem. Reviews, 89:2 (2020), 225–249
Svetlana F. Malysheva, Vladimir A. Kuimov, Natalia A. Belogorlova, Alexander I. Albanov, Nina K. Gusarova, Boris A. Trofimov, “Superbase‐Assisted Selective Synthesis of Triarylphosphines from Aryl Halides and Red Phosphorus: Three Consecutive Different SNAr Reactions in One Pot”, Eur J Org Chem, 2019:36 (2019), 6240
Deepitha John, Chinaraga Pitchaiah Kancharlapalli, Sivaraman Nagarajan, “Solubility of Phenylphosphinic Acid in Supercritical Carbon Dioxide and the Influence of Methanol on the Solubility Behavior”, J. Chem. Eng. Data, 64:12 (2019), 5775