Аннотация:
Calorimetric monitoring of the autoclave reaction N2O4 + C2H4 at –85 to +10 °C under argon pressure 10–30 bar revealed that the exothermic chemical reaction started at temperatures above –52 °C at 10 bar, whereas an intensive exothermic reaction started at –85 °C and pressure of 30 bar. IR study showed that oligo/polynitroethylene was formed at 30 bar, while carbonyl and hydroxy compound as well as nitrate R–ONO2 formation occurred upon processing at 10 bar.
Образец цитирования:
N. N. Tolkachev, E. N. Khodot, I. I. Lischiner, O. V. Malova, V. A. Tartakovsky, V. Naudet, “Effect of pressure on the low-temperature reaction of ethylene with N2O4”, Mendeleev Commun., 32:5 (2022), 597–600
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc737
https://www.mathnet.ru/rus/mendc/v32/i5/p597
Эта публикация цитируется в следующих 2 статьяx:
Eugeny N. Khodot, Iosif I. Lischiner, Valerie Naudet, Vladimir Frolov, Alexander A. Kamnev, “Infrared spectroscopic and thermographic evidence for the interaction of ethylene and 1,3-butadiene with N2O4 at cryogenic temperatures”, Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 304 (2024), 123265
Zhiwei Chu, Yingjie Li, Chunxiao Zhang, Yi Fang, Jianli Zhao, “A review on resource utilization of oil sludge based on pyrolysis and gasification”, Journal of Environmental Chemical Engineering, 11:3 (2023), 109692
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