Аннотация:
1-(Het)aryl-3-bromoprop-2-ynones react with 2-(2-furyl)pyrrole in the Al2O3 or K2CO3 dispersion (room temperature, 1 h) to afford the cross-coupling products either at the furan or pyrrole rings. Furan and 2-methylfuran with 3-bromo-1-phenylprop-2-ynone under the same conditions give the Diels–Alder cycloadducts, while furan-2-carbaldehyde andits acetals are inactive.
Тип публикации:
Статья
Язык публикации: английский
Образец цитирования:
D. N. Tomilin, L. N. Sobenina, M. D. Gotsko, I. A. Ushakov, B. A. Trofimov, “Reaction of 1-(het)aryl-3-bromoprop-2-ynones with furans in solid metal oxides or salts: cross-coupling or cycloaddition?”, Mendeleev Commun., 28:1 (2018), 20–21
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc1648
https://www.mathnet.ru/rus/mendc/v28/i1/p20
Эта публикация цитируется в следующих 2 статьяx:
M. Sahrane, K. Marakchi, R. Ghailane, “Theoretical study of the Diels–Alder reaction of 3-bromo-1-phenylprop-2-ynone with furan and 2-methylfuran”, Theor Chem Acc, 140:8 (2021)
Lyubov N. Sobenina, Denis N. Tomilin, Maxim D. Gotsko, Igor A. Ushakov, Boris A. Trofimov, “Transition metal-free cross-coupling of furan ring with haloacetylenes”, Tetrahedron, 74:13 (2018), 1565