Abstract:
The article presents a brief review of works on the refinement of the $\rm Zr$–$\rm C$ phase diagram: the parameters of the solidus and liquidus lines, the temperature and composition of congruently melting carbide, and the $\rm ZrC$–$\rm C$ eutectic temperature. We consider the experimental data on the heat of fusion and the specific heat of liquid $\mathrm{ZrC}_x$ obtained by electrical-pulse heating (previously presented only in graphical form). The $C_p(T)$ curve is numerically processed, and an equation is presented that approximates the temperature dependence of the specific heat of liquid zirconium carbide $\mathrm{ZrC}_x\,([\mathrm{C}]/[\mathrm{Zr}] = 0.95)$ from the melting point at $3840$ K to $5000$ K.
Citation:
N. M. Aristova, S. V. Onufriev, A. I. Savvatimskii, “Specific heat of liquid zirconium carbide $\rm ZrC_{0.95}$ at temperatures up to $5000$ K”, TVT, 58:5 (2020), 749–757; High Temperature, 58:5 (2020), 681–688
\Bibitem{AriOnuSav20}
\by N.~M.~Aristova, S.~V.~Onufriev, A.~I.~Savvatimskii
\paper Specific heat of liquid zirconium carbide $\rm ZrC_{0.95}$ at temperatures up to $5000$~K
\jour TVT
\yr 2020
\vol 58
\issue 5
\pages 749--757
\mathnet{http://mi.mathnet.ru/tvt11364}
\crossref{https://doi.org/10.31857/S0040364420050014}
\elib{https://elibrary.ru/item.asp?id=43962079}
\transl
\jour High Temperature
\yr 2020
\vol 58
\issue 5
\pages 681--688
\crossref{https://doi.org/10.1134/S0018151X20050016}
\isi{https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=Publons&SrcAuth=Publons_CEL&DestLinkType=FullRecord&DestApp=WOS_CPL&KeyUT=000601547100002}
\scopus{https://www.scopus.com/record/display.url?origin=inward&eid=2-s2.0-85098002973}
Linking options:
https://www.mathnet.ru/eng/tvt11364
https://www.mathnet.ru/eng/tvt/v58/i5/p749
This publication is cited in the following 3 articles:
N. M. Aristova, G. V. Belov, “Thermodynamic properties of $\rm ZrC_{0.95-0.99}$ zirconium carbide in a condensed state”, High Temperature, 60:1 (2022), 19–27
A. I. Savvatimskiy, S. V. Onufriev, N. M. Aristova, “Physical properties of refractory carbides of metals of groups IV and V of the Mendeleev periodic table during rapid heating by an electric current pulse”, Phys. Usp., 65:6 (2022), 597–616
S. N. Grigoriev, Kh. Hamdy, M. A. Volosova, A. A. Okunkova, S. V. Fedorov, “Electrical discharge machining of oxide and nitride ceramics: a review”, Mater. Des., 209 (2021), 109965