Abstract:
Based on the specific heat equations obtained earlier for crystalline $(298.15$–$3840$ K$)$ and liquid $(3840$–$5000$ K$)$ zirconium carbide with composition close to stoichiometric, we calculated the thermodynamic functions for $\rm ZrC_{0.95-0.99}$ at temperatures of $100$ to $5000$ K. Special attention is paid to the nature of the anomalous growth of the enthalpy and the specific heat of the crystalline $\mathrm{ZrC}_x$ at temperatures above $\sim2200$ K. The calculated thermodynamic functions are included in the IVTANTHERMO database.
Citation:
N. M. Aristova, G. V. Belov, “Thermodynamic properties of $\rm ZrC_{0.95-0.99}$ zirconium carbide in a condensed state”, TVT, 60:1 (2022), 23–32; High Temperature, 60:1 (2022), 19–27
\Bibitem{AriBel22}
\by N.~M.~Aristova, G.~V.~Belov
\paper Thermodynamic properties of $\rm ZrC_{0.95-0.99}$ zirconium carbide in a~condensed state
\jour TVT
\yr 2022
\vol 60
\issue 1
\pages 23--32
\mathnet{http://mi.mathnet.ru/tvt11531}
\crossref{https://doi.org/10.31857/S004036442201001X}
\elib{https://elibrary.ru/item.asp?id=48506024}
\transl
\jour High Temperature
\yr 2022
\vol 60
\issue 1
\pages 19--27
\crossref{https://doi.org/10.1134/S0018151X22010242}
Linking options:
https://www.mathnet.ru/eng/tvt11531
https://www.mathnet.ru/eng/tvt/v60/i1/p23
This publication is cited in the following 1 articles:
A. I. Savvatimskiy, S. V. Onufriev, N. M. Aristova, “Physical properties of refractory carbides of metals of groups IV and V of the Mendeleev periodic table during rapid heating by an electric current pulse”, Phys. Usp., 65:6 (2022), 597–616