Abstract:
The review summarizes data published in the last decade on the reactions of organic compounds involving N-acyliminium ions, including intramolecular arylation (cyclization), cross-coupling with nucleophiles and some other transformations to form new carbon–carbon and carbon–heteroatom bonds. The stereo- and enantioselective versions of these reactions using chiral auxiliaries and asymmetric catalysts (organocatalysts) are considered. Examples of application of N-acyliminium ions for the synthesis of natural compounds and their analogues are presented. The bibliography includes 100 references.
Citation:
M. G. Vinogradov, O. V. Turova, S. G. Zlotin, “The progress in the chemistry of N-acyliminium ions and their use in stereoselective organic synthesis”, Russian Chem. Reviews, 86:1 (2017), 1–17
\Bibitem{VinTurZlo17}
\by M.~G.~Vinogradov, O.~V.~Turova, S.~G.~Zlotin
\paper The progress in the chemistry of N-acyliminium ions and their use in stereoselective organic synthesis
\jour Russian Chem. Reviews
\yr 2017
\vol 86
\issue 1
\pages 1--17
\mathnet{http://mi.mathnet.ru/eng/rcr4145}
\crossref{https://doi.org/10.1070/RCR4628}
\adsnasa{https://adsabs.harvard.edu/cgi-bin/bib_query?2017RuCRv..86....1V}
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Linking options:
https://www.mathnet.ru/eng/rcr4145
https://doi.org/10.1070/RCR4628
https://www.mathnet.ru/eng/rcr/v86/i1/p1
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