Abstract:
The principal results of studies on trivalent phosphorus acid amides (TPAA) as phosphorylating agents for alcohols, phenols, and amines are summarised and discussed. Problems concerning the catalysis and mechanism of the phosphorylation of proton-donating nucleophiles by TPAA are considered and new possibilities for the development of investigations on these lines are analysed. The preparative advantages of TPAA and the specific prospects for their use in fine organic synthesis and macromolecular chemistry are demonstrated. The bibliography includes 560 references.
Received: 23.05.1994
Bibliographic databases:
Document Type:
Article
UDC:
547.953+547.91
Language: English
Original paper language: Russian
Citation:
E. E. Nifantyev, M. K. Grachev, “Trivalent phosphorus acids amides as phosphorylating agents for alcohols and amines”, Usp. Khim., 63:7 (1994), 602–637; Russian Chem. Reviews, 63:7 (1994), 575–609
Linking options:
https://www.mathnet.ru/eng/rcr1182
https://doi.org/10.1070/RC1994v063n07ABEH000106
https://www.mathnet.ru/eng/rcr/v63/i7/p602
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I. S. Antipin, E. Kh. Kazakova, W. D. Habicher, A. I. Konovalov, Russian Chem. Reviews, 67:11 (1998), 905–922
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E. E. Nifantyev, M. K. Grachev, Russian Chem. Reviews, 63:7 (1994), 575–609
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