Abstract:
Isotherms obtained on the basis of a new distribution are compared with isotherms of the famous van der Waals model, using a language easily understood by engineers and undergraduates (without proofs or theorems, which can be found in the given references, but with elementary examples and simple associations). We propose a new interpretation of the van der Waals model. On the Hougen–Watson diagram, the domain where the mixing of gases occurs with maximum rate is indicated. A new distribution is presented, the notion of new ideal gas is introduced, and the invariants of the isotherms introduced by the author are explained.
Keywords:
isotherm, isochore, number of collective degrees of freedom,
admissible cluster size, Boltzmann–Maxwell ideal gas, Lagrangian manifold,
tunnel classical operator, focal point, jamming effect, critical point, opalescence.
Maslov V.P., “a New Distribution Corresponding To Thermodynamics in Supercritical and Subcritical Regions and in the Region of Negative Pressure”, Dokl. Math., 91:3 (2015), 379–383