Abstract:
We define a new property of the spinodal as the curve with maximum Hartley entropy. We give a method for constructing the gas spinodal and isotherms with the help of the second and third virial coefficients. A “gas–amorphous body” phase transition is considered.
This publication is cited in the following 3 articles:
Maslov V.P., “Van der Waals Equation From the Viewpoint of Probability Distribution and the Triple Point as the Critical Point of the Liquid-To-Solid Transition”, Russ. J. Math. Phys., 22:2 (2015), 188–200
V. P. Maslov, “Gas–Amorphous Solid and Liquid–Amorphous Solid Phase Transitions. Introduction of Negative Mass and Pressure from the Mathematical Viewpoint”, Math. Notes, 97:3 (2015), 423–430
V. P. Maslov, T. V. Maslova, “New Thermodynamics and Frost Cleft in Conifers”, Math. Notes, 98:2 (2015), 343–347