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Mendeleev Communications, 2023, Volume 33, Issue 1, Pages 45–46
DOI: https://doi.org/10.1016/j.mencom.2023.01.013 (Mi mendc302) 		 
This article is cited in 2 scientific papers (total in 2 papers)

Communications

New chain polymer [Yb(tpa)(H2O)2Co(CN)6]n · 7n H2O: synthesis, structure, and magnetic characteristics

S. P. Petrosyants, A. B. Ilyukhin, K. A. Babeshkin, N. N. Efimov, P. S. Koroteev

N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
Full-text PDF (443 kB) Citations (2)
DOI: https://doi.org/10.1016/j.mencom.2023.01.013
Abstract: The 3d– 4f heterometallic polymeric complex, namely [Yb(tpa)(H2O)2Co(CN)6]n·7n H2O [tpa = tris(2-pyridylmethyl)- amine], was synthesized and characterized. Its polymer structure is formed of [Yb(tpa)(H2O)2Co(CN)6] chains and crystallization water molecules with a two-capped trigonal prism Yb3+ coordination polyhedron; the Yb3+ coordination number is 8, and the coordination site is YbN6O2. Magnetic characteristics indicate that the complex exhibits the properties of a single-chain magnet with a magnetization reversal barrier(!E/kB) of 42 K.
Keywords: ytterbium, heterometallic complexes, cyanometallate chains, coordination polymers, single-molecule magnets.
Document Type: Article
Language: English
Supplementary materials:
Supplementary_data_1.pdf (699.5 Kb)


Citation: S. P. Petrosyants, A. B. Ilyukhin, K. A. Babeshkin, N. N. Efimov, P. S. Koroteev, “New chain polymer [Yb(tpa)(H2O)2Co(CN)6]n · 7n H2O: synthesis, structure, and magnetic characteristics”, Mendeleev Commun., 33:1 (2023), 45–46
Linking options:
  • https://www.mathnet.ru/eng/mendc302
  • https://www.mathnet.ru/eng/mendc/v33/i1/p45
    • This publication is cited in the following 2 articles:
    1. Andrey V. Gavrikov, Andrey B. Ilyukhin, Ilya V. Taydakov, Mikhail T. Metlin, Nikolay P. Datskevich, Mikhail E. Buzoverov, Konstantin A. Babeshkin, Nikolay N. Efimov, “Novel stable ytterbium acetylacetonate–quinaldinate complexes as single-molecule magnets and surprisingly efficient luminophores”, Dalton Trans., 52:47 (2023), 17911  crossref
    2. E. Gungor, “SYNTHESIS, CRYSTAL STRUCTURE, SPECTROSCOPIC, LUMINESCENCE STUDIES AND HIRSHFELD SURFACE ANALYSIS OF BLUE LIGHT EMITTING HETEROMETALLIC MnIII–NiII COMPLEX”, J Struct Chem, 64:9 (2023), 1780  crossref
    Citing articles in Google Scholar: Russian citations, English citations
    Related articles in Google Scholar: Russian articles, English articles
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