I. Solovyev, D. Dar’in, M. Krasavin, “Diazo chemistry in the access to novel fatty acids linked to spiro-fused oxetane-pyrazolone scaffold”, Mendeleev Commun., 33:1 (2023), 21

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Mendeleev Communications, 2023, Volume 33, Issue 1, Pages 21–23
DOI: https://doi.org/10.1016/j.mencom.2023.01.006 (Mi mendc295)

This article is cited in 1 scientific paper (total in 1 paper)

Communications

Diazo chemistry in the access to novel fatty acids linked to spiro-fused oxetane-pyrazolone scaffold

I. Solovyev^a, D. Dar’in^a, M. Krasavin^ab

^a Institute of Chemistry, St. Petersburg State University, St. Petersburg, Russian Federation
^b Immanuel Kant Baltic Federal University, Kaliningrad, Russian Federation

Full-text PDF (171 kB) Citations (1)

DOI: https://doi.org/10.1016/j.mencom.2023.01.006

Graphic abstract: Diazo chemistry in the access to novel fatty acids linked to spiro-fused oxetane-pyrazolone scaffold

Abstract: A novel free fatty acid mimetic based on the spirocyclic oxetane pyrazolone 1-oxa-6,7-diazaspiro[3.4]oct-7-en-5-one scaffold has been obtained in seven steps. The key stages are based upon the toolbox of diazo chemistry, including the F SAFE diazo transfer and Rh^II-catalyzed O–H insertion followed by base-triggered oxetane closing.

Keywords: fatty acid mimetics, free fatty acid receptor 1, GPR40, spiro compounds, pyrazolone, oxetanes, rhodium(II)-catalyzed O–H insertion, intramolecular S_N2 reaction.

Document Type: Article

Language: English

*Supplementary materials:*
		Supplementary_data_1.pdf	(836.6 Kb)

Citation: I. Solovyev, D. Dar’in, M. Krasavin, “Diazo chemistry in the access to novel fatty acids linked to spiro-fused oxetane-pyrazolone scaffold”, Mendeleev Commun., 33:1 (2023), 21–23

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https://www.mathnet.ru/eng/mendc295

https://www.mathnet.ru/eng/mendc/v33/i1/p21

This publication is cited in the following 1 articles:

Ramón M. Sánchez, Josefa Anaya, Progress in Heterocyclic Chemistry, 36, Progress in Heterocyclic Chemistry (PHC), 2024, 59

Citing articles in Google Scholar: Russian citations, English citations
Related articles in Google Scholar: Russian articles, English articles

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