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Mendeleev Communications, 2013, Volume 23, Issue 3, Pages 135–136
DOI: https://doi.org/10.1016/j.mencom.2013.05.004
(Mi mendc2638)
 

This article is cited in 6 scientific papers (total in 6 papers)

Communications

Synthesis, X-ray crystal structure and quantum-chemical study of new dinuclear cobalt complex {Co2[mmm-O2P(H)Mes]2(bpy)4}Br2

E. A. Trofimovaa, A. B. Dobrynina, T. P. Gerasimovaa, S. A. Katsyubaa, O. G. Sinyashina, D. G. Yakhvarovab

a A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, Kazan, Russian Federation
b Alexander Butlerov Institute of Chemistry, Kazan Federal University, Kazan, Russian Federation
Full-text PDF (320 kB) Citations (6)
Abstract: The reaction of cobalt dibromide hexahydrate with 2,2’-bipyridine (bpy) and mesitylphosphinic acid MesP(O)(OH)H (Mes = = 2,4,6-trimethylphenyl) under solvothermal synthesis conditions leads to a new dinuclear cobalt(ii) complex {Co2[µ-O2P(H)Mes]2- (bpy)4}Br2 formed by two bridging {µ-O2P(H)Mes}– ligands. X-ray crystal structure analysis of the complex displayed that cobalt ions have distorted octahedral coordination and are doubly bridged by two mesitylphosphinato ligands.
Keywords: 2,2'-bipyridine, bridging phosphinate ligands, dinuclear cobalt complexes, X-Ray crystal structure, quantum-chemical study.
Document Type: Article
Language: English
Supplementary materials:
Supplementary_data_1.pdf (473.5 Kb)


Citation: E. A. Trofimova, A. B. Dobrynin, T. P. Gerasimova, S. A. Katsyuba, O. G. Sinyashin, D. G. Yakhvarov, “Synthesis, X-ray crystal structure and quantum-chemical study of new dinuclear cobalt complex {Co2[mmm-O2P(H)Mes]2(bpy)4}Br2”, Mendeleev Commun., 23:3 (2013), 135–136
Linking options:
  • https://www.mathnet.ru/eng/mendc2638
  • https://www.mathnet.ru/eng/mendc/v23/i3/p135
  • This publication is cited in the following 6 articles:
    1. M. A. Agafonov, E. V. Alexandrov, N. A. Artyukhova, G. E. Bekmukhamedov, V. A. Blatov, V. V. Butova, Y. M. Gayfulin, A. A. Garibyan, Z. N. Gafurov, Yu. G. Gorbunova, L. G. Gordeeva, M. S. Gruzdev, A. N. Gusev, G. L. Denisov, D. N. Dybtsev, Yu. Yu. Enakieva, A. A. Kagilev, A. O. Kantyukov, M. A. Kiskin, K. A. Kovalenko, A. M. Kolker, D. I. Kolokolov, Y. M. Litvinova, A. A. Lysova, N. V. Maksimchuk, Y. V. Mironov, Yu. V. Nelyubina, V. V. Novikov, V. I. Ovcharenko, A. V. Piskunov, D. M. Polyukhov, V. A. Polyakov, V. G. Ponomareva, A. S. Poryvaev, G. V. Romanenko, A. V. Soldatov, M. V. Solovyeva, A. G. Stepanov, I. V. Terekhova, O. Yu. Trofimova, V. P. Fedin, M. V. Fedin, O. A. Kholdeeva, A. Yu. Tsivadze, U. V. Chervonova, A. I. Cherevko, V. F. Shul′gin, E. S. Shutova, D. G. Yakhvarov, “METAL-ORGANIC FRAMEWORKS IN RUSSIA: FROM THE SYNTHESIS AND STRUCTURE TO FUNCTIONAL PROPERTIES AND MATERIALS”, J Struct Chem, 63:5 (2022), 671  crossref
    2. N. K. Gusarova, A. O. Sutyrina, V. A. Kuimov, S. F. Malysheva, N. A. Belogorlova, P. A. Volkov, B. A. Trofimov, “Single-stage synthesis of alkyl-H-phosphinic acids from elemental phosphorus and alkyl bromides”, Mendeleev Commun., 29:3 (2019), 328–330  mathnet  crossref
    3. Amanda N. Graveson, Celia M. Gendron-Herndon, Alexander N. Erickson, Carolyn N. Virca, Michael A. Paton, Edward J. Valente, Eugenijus Urnezius, “Discrete bimetallic Co(II) phosphinate complexes supported by 2,6-dimesitylphenylphosphinate ligand”, Polyhedron, 123 (2017), 14  crossref
    4. Tatiana P. Gerasimova, Sergey A. Katsyuba, Ludmila G. Lavrenova, Vladimir Pelmenschikov, Martin Kaupp, “Correlations between metal spin states and vibrational spectra of a trinuclear Fe(II) complex exhibiting spin crossover”, Journal of Molecular Structure, 1101 (2015), 8  crossref
    5. D. G. Yakhvarov, E. A. Trofimova, A. B. Dobrynin, T. P. Gerasimova, S. A. Katsyuba, O. G. Sinyashin, “First neutral dinuclear cobalt complex formed by bridging [μ-O2P(H)R]– ligands: synthesis, X-ray crystal structure and quantum-chemical study”, Mendeleev Commun., 25:1 (2015), 27–28  mathnet  crossref
    6. I. S. Kovalev, D. S. Kopchuk, A. F. Khasanov, G. V. Zyryanov, V. L. Rusinov, O. N. Chupakhin, “The synthesis of polyarene-modified 5-phenyl-2,2'-bipyridines via the SHN methodology and aza-Diels–Alder reaction”, Mendeleev Commun., 24:2 (2014), 117–118  mathnet  crossref
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