Abstract:
The reaction of cobalt dibromide hexahydrate with 2,2’-bipyridine (bpy) and 9-anthrylphosphinic acid AntP(O)(OH)H (Ant = 9-anthryl) leads to the first example of a neutral dinuclear cobalt(ii) complex {Co2Br2[μ-O2P(H)Ant]2(bpy)2} formed by two bridging [μ-O2P(H)Ant]– ligands. The complex has been characterized by X-ray diffraction analysis and quantum-chemical calculations.
Citation:
D. G. Yakhvarov, E. A. Trofimova, A. B. Dobrynin, T. P. Gerasimova, S. A. Katsyuba, O. G. Sinyashin, “First neutral dinuclear cobalt complex formed by bridging [μ-O2P(H)R]– ligands: synthesis, X-ray crystal structure and quantum-chemical study”, Mendeleev Commun., 25:1 (2015), 27–28
Linking options:
https://www.mathnet.ru/eng/mendc2288
https://www.mathnet.ru/eng/mendc/v25/i1/p27
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