Abstract:
Novel highly functionalized and pharmacologically promising active silatranes equipped with an α,β-unsaturated imine group, Het(Ar)CH=C(SR)C(H)=N–, in the axial chain have been synthesized by the reaction of 3-aminopropylsilatrane and (Z)-2-alkylthio-3-(het)arylpropenals. The structures of these compounds were characterized by IR and 1H, 13C, 15N, 29Si, 1D and 2D NMR spectroscopy.
Document Type:
Article
Language: English
Citation:
S. N. Adamovich, N. V. Vchislo, E. N. Oborina, I. A. Ushakov, I. B. Rozentsveig, “Novel α,β-unsaturated imine derivatives of 3-aminopropylsilatrane”, Mendeleev Commun., 27:5 (2017), 443–445
Linking options:
https://www.mathnet.ru/eng/mendc2020
https://www.mathnet.ru/eng/mendc/v27/i5/p443
This publication is cited in the following 9 articles:
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Nadezhda V. Vchislo, Sergey N. Adamovich, Victoria G. Fedoseeva, Elizaveta N. Oborina, Igor B. Rozentsveig, Francis Verpoort, “Schiff Base of 3‐Aminopropylalkoxysilanes and 3‐Aminopropylsilatranes: Importance of Investigations and the Potential Applications”, Applied Organom Chemis, 38:12 (2024)
Mirela-Fernanda Zaltariov, Mihaela Turtoi, Dragos Peptanariu, Ana-Maria Macsim, Lilia Clima, Corneliu Cojocaru, Nicoleta Vornicu, Bianca-Iulia Ciubotaru, Alexandra Bargan, Manuela Calin, Maria Cazacu, “Chemical Attachment of 5-Nitrosalicylaldimine Motif to Silatrane Resulting in an Organic–Inorganic Structure with High Medicinal Significance”, Pharmaceutics, 14:12 (2022), 2838
S. N. Adamovich, I. A. Ushakov, A. V. Afonin, N. V. Vchislo, E. N. Oborina, D. V. Pavlov, “O- and S-containing 1-azadiene derivatives of 3-aminopropylsilatrane”, Russ Chem Bull, 70:2 (2021), 406
N.F. Lazareva, I.V. Sterkhova, “1-[N-phenyl(aminomethyl)]silatrane: Synthesis, reactivity and structure”, Journal of Organometallic Chemistry, 898 (2019), 120870
S. N. Adamovich, E. N. Oborina, “Metallatranes and hydrometallatranes: their immunotropic and antitumor properties”, Russ Chem Bull, 68:9 (2019), 1723
Z. G. Denieva, U. A. Budanova, Yu. L. Sebyakin, “Synthetic asymmetric lipid-like organosilanes for liposomal nanohybrid cerasomes toward potential medical applications”, Mendeleev Commun., 29:1 (2019), 32–34
S. N. Adamovich, V. V. Novokshonov, I. A. Ushakov, V. G. Elshina, E. N. Oborina, “New silatranes of α,β-acetylene azomethine series”, Russ Chem Bull, 67:9 (2018), 1744
V. I. Smirnov, E. A. Zelbst, G. A. Kuznetsova, I. V. Sterkhova, “Crystal and molecular structures of Si-(iodomethyl)silatranes with methyl substituents in β-position relative to the nitrogen atom”, Mendeleev Commun., 28:3 (2018), 278–280
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