Abstract:
A new organic-inorganic hybrid material composed of 0-D bromobismuthate anions and bis(4-cyano-1-pyridino)pentane cations was synthesized and characterized. The replacement of Br with I resulted in a decrease in the optical band gap from 2.88 eV for (C17H18N4)2Bi2Br10 to 1.59 eV for (C17H18N4)BiI5. Thus, (C17H18N4)BiI5 can be proposed as a candidate material for solid state solar cells.
Citation:
V. Yu. Kotov, A. B. Ilyukhin, A. A. Sadovnikov, K. P. Birin, N. P. Simonenko, H. T. Nguyen, A. Y. Baranchikov, S. A. Kozyukhin, “Bis(4-cyano-1-pyridino)pentane halobismuthates. Light-harvesting material with an optical band gap of 1.59 eV”, Mendeleev Commun., 27:3 (2017), 271–273
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P. A. Buikin, A. Yu. Rudenko, A. B. Ilyukhin, N. P. Simonenko, Kh. E. Yorov, V. Yu. Kotov, “Bromobismuthates of 1,1'-(1,N-Alkanediyl)bis(picolines): Synthesis, Thermal Stability, Crystal Structures, and Optical Properties”, Russ J Coord Chem, 46:2 (2020), 111
Vitalii Yu. Kotov, Elnara S. Safiullina, Andrey B. Ilyukhin, Petr A. Buikin, Kirill P. Birin, Khursand E. Yorov, “Hybrid halobismuthates: The unusual {[BiBr6]…[BiBr5]…[BiBr6]}8- anionic framework”, Journal of Molecular Structure, 1195 (2019), 944
Sergey A. Adonin, Igor D. Gorokh, Alexander S. Novikov, Andrey N. Usoltsev, Maxim N. Sokolov, Vladimir P. Fedin, “Tetranuclear anionic bromobismuthate [Bi4Br18]6-: New structural type in halometalate collection”, Inorganic Chemistry Communications, 103 (2019), 72
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