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Mendeleev Communications, 2017, Volume 27, Issue 3, Pages 271–273
DOI: https://doi.org/10.1016/j.mencom.2017.05.018
(Mi mendc1965)
 

This article is cited in 29 scientific papers (total in 29 papers)

Communications

Bis(4-cyano-1-pyridino)pentane halobismuthates. Light-harvesting material with an optical band gap of 1.59 eV

V. Yu. Kotovab, A. B. Ilyukhina, A. A. Sadovnikova, K. P. Birinc, N. P. Simonenkoa, H. T. Nguyena, A. Y. Baranchikovad, S. A. Kozyukhina

a N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
b Higher Chemical College of the Russian Academy of Sciences, D.I. Mendeleev University of Chemical Technology of Russia, Moscow, Russian Federation
c A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, Russian Federation
d Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
Abstract: A new organic-inorganic hybrid material composed of 0-D bromobismuthate anions and bis(4-cyano-1-pyridino)pentane cations was synthesized and characterized. The replacement of Br with I resulted in a decrease in the optical band gap from 2.88 eV for (C17H18N4)2Bi2Br10 to 1.59 eV for (C17H18N4)BiI5. Thus, (C17H18N4)BiI5 can be proposed as a candidate material for solid state solar cells.
Document Type: Article
Language: English
Supplementary materials:
Supplementary_data_1.pdf (976.0 Kb)


Citation: V. Yu. Kotov, A. B. Ilyukhin, A. A. Sadovnikov, K. P. Birin, N. P. Simonenko, H. T. Nguyen, A. Y. Baranchikov, S. A. Kozyukhin, “Bis(4-cyano-1-pyridino)pentane halobismuthates. Light-harvesting material with an optical band gap of 1.59 eV”, Mendeleev Commun., 27:3 (2017), 271–273
Linking options:
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  • https://www.mathnet.ru/eng/mendc/v27/i3/p271
  • This publication is cited in the following 29 articles:
    1. Mikhail A. Bondarenko, Alexander S. Novikov, Pavel A. Abramov, Maxim N. Sokolov, Sergey A. Adonin, “Crystalline products of bromoantimonate(iii) oxidation by Br2 in the presence of different cations: diversity of structural types and patterns of halogen bond systems”, CrystEngComm, 26:33 (2024), 4518  crossref
    2. A. N. Usoltsev, I. V. Korol'kov, S. A. Adonin, “Bromoantimonates(III) vs. Bromobismuthates(III): Differences in the Tendency for the Formation of Polynuclear Complexes”, Russ J Coord Chem, 49:6 (2023), 345  crossref
    3. Zumaira Siddique, Julia L. Payne, Muhammad Tariq Sajjad, Natalie Mica, David B. Cordes, Alexandra M. Z. Slawin, Ifor D. W. Samuel, Azhar Iqbal, John T. S. Irvine, “Synthesis and optical characterization of lead-free phenylenediammonium bismuth halide perovskites: a long charge carrier lifetime in phenylenediammonium bismuth iodide”, J. Mater. Chem. C, 11:1 (2023), 223  crossref
    4. A. N. Usoltsev, I. V. Korol'kov, S. A. Adonin, “Bromoantimonates(III) vs. Bromobismuthates(III): Differences in the Tendency for the Formation of Polynuclear Complexes”, Koordinacionnaâ himiâ, 49:6 (2023), 341  crossref
    5. Andrey V. Bykov, Tatiana A. Shestimerova, Mikhail A. Bykov, Konstantin A. Lyssenko, Vladislav M. Korshunov, Mikhail T. Metlin, Ilya V. Taydakov, Andrei V. Shevelkov, “Molecular and Supramolecular Structure of a New Luminescent Hybrid Compound: (C5N2H14)2[BiBr6]Br·H2O”, Inorganics, 10:11 (2022), 181  crossref
    6. T. A. Shestimerova, M. A. Bykov, A. V. Grigor'eva, Zh. Wei, E. V. Dikarev, A. V. Shevelkov, “Synthesis and characterization of amantadinium iodoacetatobismuthate, a hybrid compound with mixed iodide–carboxylate anions”, Mendeleev Commun., 32:2 (2022), 194–197  mathnet  crossref
    7. Andrey N. Usoltsev, Nikita A. Korobeynikov, Alexander S. Novikov, Vladimir R. Shayapov, Ilya V. Korolkov, Denis G. Samsonenko, Vladimir P. Fedin, Maxim N. Sokolov, Sergey A. Adonin, “One-Dimensional Supramolecular Hybrid Iodobismuthate (1-EtPy)3{[Bi2I9](I2)0.75}: Structural Features and Theoretical Studies of I···I Non-Covalent Interactions”, J Clust Sci, 32:3 (2021), 787  crossref
    8. Tatiana A. Shestimerova, Andrei V. Mironov, Mikhail A. Bykov, Elizaveta D. Starichenkova, Alexey N. Kuznetsov, Anastasia V. Grigorieva, Andrei V. Shevelkov, “Reversal Topotactic Removal of Acetone from (HMTH)2BiI5·(CH3)2C═O Accompanied by Rearrangement of Weak Bonds, from 1D to 3D Patterns”, Crystal Growth & Design, 20:1 (2020), 87  crossref
    9. Tatiana A. Shestimerova, Andrei V. Mironov, Mikhail A. Bykov, Anastasia V. Grigorieva, Zheng Wei, Evgeny V. Dikarev, Andrei V. Shevelkov, “Assembling Polyiodides and Iodobismuthates Using a Template Effect of a Cyclic Diammonium Cation and Formation of a Low-Gap Hybrid Iodobismuthate with High Thermal Stability”, Molecules, 25:12 (2020), 2765  crossref
    10. Vitalii Yu. Kotov, Petr A. Buikin, Nikolay P. Simonenko, Andrey B. Ilyukhin, “Hybrid bromobismuthates: Synthesis, thermal stability and crystal structure of multicharged 3-ammoniopyridinium derivatives”, Journal of Molecular Structure, 1221 (2020), 128807  crossref
    11. P. A. Buikin, A. Yu. Rudenko, A. B. Ilyukhin, N. P. Simonenko, Kh. E. Yorov, V. Yu. Kotov, “Bromobismuthates of 1,1'-(1,N-Alkanediyl)bis(picolines): Synthesis, Thermal Stability, Crystal Structures, and Optical Properties”, Russ J Coord Chem, 46:2 (2020), 111  crossref
    12. Vitalii Yu. Kotov, Elnara S. Safiullina, Andrey B. Ilyukhin, Petr A. Buikin, Kirill P. Birin, Khursand E. Yorov, “Hybrid halobismuthates: The unusual {[BiBr6]…[BiBr5]…[BiBr6]}8- anionic framework”, Journal of Molecular Structure, 1195 (2019), 944  crossref
    13. Sergey A. Adonin, Igor D. Gorokh, Alexander S. Novikov, Andrey N. Usoltsev, Maxim N. Sokolov, Vladimir P. Fedin, “Tetranuclear anionic bromobismuthate [Bi4Br18]6-: New structural type in halometalate collection”, Inorganic Chemistry Communications, 103 (2019), 72  crossref
    14. Vitalii Yu. Kotov, Andrey B. Ilyukhin, Petr A. Buikin, Nikolay P. Simonenko, Alexander A. Korlyukov, Alexander F. Smol'yakov, Khursand E. Yorov, Andrey V. Gavrikov, “Unexpected hydrolytic transformation of new type hybrid bromobismuthates with methylpyrazinium dications”, Dalton Trans., 48:22 (2019), 7602  crossref
    15. S. A. Adonin, M. A. Bondarenko, P. A. Abramov, I. V. Korolkov, P. E. Plyusnin, M. N. Sokolov, V. P. Fedin, “Mononuclear Sb(V) Bromide Complexes with 3-Halopyridinium Cations: Synthesis, Structures, and Thermal Stability”, Russ J Coord Chem, 45:2 (2019), 128  crossref
    16. V. Yu. Kotov, A. B. Ilyukhin, P. A. Buikin, Kh. E. Yorov, “Mixed halide hybrid halobismuthates and their in situ transformations”, Mendeleev Commun., 29:5 (2019), 537–540  mathnet  crossref
    17. A. A. Semenova, A. B. Tarasov, E. A. Goodilin, “Periodic table of elements and nanotechnology”, Mendeleev Commun., 29:5 (2019), 479–485  mathnet  crossref
    18. Tatiana A. Shestimerova, Nikita A. Golubev, Natallia A. Yelavik, Mikhail A. Bykov, Anastasia V. Grigorieva, Zheng Wei, Evgeny V. Dikarev, Andrei V. Shevelkov, “Role of I2 Molecules and Weak Interactions in Supramolecular Assembling of Pseudo-Three-Dimensional Hybrid Bismuth Polyiodides: Synthesis, Structure, and Optical Properties of Phenylenediammonium Polyiodobismuthate(III)”, Crystal Growth & Design, 18:4 (2018), 2572  crossref
    19. Vitalii Yu. Kotov, Andrey B. Ilyukhin, Alaxander E. Baranchikov, Rashida I. Ishmetova, Gennady L. Rusinov, Sergey A. Kozyukhin, “Synthesis, crystal structure and optical properties of 1,1'-(1,n-alkanediyl)bis(3-methylimidazolium) halobismuthates”, Journal of Molecular Structure, 1151 (2018), 186  crossref
    20. Vitalii Yu. Kotov, Andrey B. Ilyukhin, Alexander A. Korlyukov, Alexander F. Smol'yakov, Sergey A. Kozyukhin, “Black hybrid iodobismuthate containing linear anionic chains”, New J. Chem., 42:8 (2018), 6354  crossref
    Citing articles in Google Scholar: Russian citations, English citations
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