Abstract:
The amantadinium iodoacetatobismuthate(III) [C10H15NH3·(CH3)2CO]2[BiI3.67(CH3COO)1.33] is a new hybrid halometallate with iodide ions partially replaced by oxygen-containing acetates to form stronger interaction between the anionic and cationic substructures. The title compound as well-shaped orange-red crystals was synthesized by a facile reaction in acetone solution in the presence of glacial acetic acid. The crystal structure of the compound consists of the infinite anionic chains [BiI3.67(CH3COO)1.33]2– and the countercations [C10H15NH3·(CH3)2CO]+; according to the optical absorption data, the test compound is a semiconductor with a band gap of 2.06 eV.
Citation:
T. A. Shestimerova, M. A. Bykov, A. V. Grigor'eva, Zh. Wei, E. V. Dikarev, A. V. Shevelkov, “Synthesis and characterization of amantadinium iodoacetatobismuthate, a hybrid compound with mixed iodide–carboxylate anions”, Mendeleev Commun., 32:2 (2022), 194–197
Linking options:
https://www.mathnet.ru/eng/mendc611
https://www.mathnet.ru/eng/mendc/v32/i2/p194
This publication is cited in the following 3 articles:
L. N. Zelenina, T. P. Chusova, N. A. Korobeinikov, A. N. Usoltsev, “Termodinamicheskoe issledovanie polibromidnykh kompleksov tellura”, Russian Journal of Physical Chemistry, 98:1 (2024), 52
L. N. Zelenina, T. P. Chusova, N. A. Korobeinikov, A. N. Usol'tsev, “Thermodynamic Study of Tellurium Polybromide Complexes”, Russ. J. Phys. Chem., 98:1 (2024), 50
Rustam K. Kamilov, Jahongir Z. Yuldoshev, Alexander V. Knotko, Anastasia V. Grigorieva, “In Search of a Double Perovskite in the Phase Triangle of Bromides CsBr-CuBr-InBr3”, Materials, 16:10 (2023), 3744
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