R. Yu. Lukin, D. A. Emelyanov, A. D. Kachmarzhik, A. V. Sukhov, O. G. Sinyashin, D. G. Yakhvarov, “Effect of Buchwald-type ligands on platinum catalyzed hydrosilylation of vinyl terminated polydimethylsiloxane”, Mendeleev Commun., 29:4 (2019), 458

Abstract: The effect of Buchwald-type ligands on the platinum catalyzed hydrosilylation of vinyl-terminated polydimethylsiloxane has been studied by differential scanning calorimetry of platinum catalyst-containing silicone compositions. Dialkyl(biphenyl-2-yl)phosphines bearing bulky substituents at phosphorus atom are efficient inhibitors of the catalytic hydrosilylation process allowing one to increase the pot-life of silicone composition and to prevent the decomposition of the Pt-based catalyst.

This publication is cited in the following 9 articles:

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