A. S. Kritchenkov, A. I. Kurachenkov, A. R. Egorov, N. Z. Yagafarov, E. A. Fortalnova, N. N. Lobanov, A. P. Dysin, A. S. Khomik, V. N. Khrustalev, “Novel zinc(II)/chitosan-based composite: ultrasound-assisted synthesis, catalytic and antibacterial activity”, Mendeleev Commun., 30:5 (2020), 642

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Mendeleev Communications, 2020, Volume 30, Issue 5, Pages 642–644
DOI: https://doi.org/10.1016/j.mencom.2020.09.030 (Mi mendc1279)

This article is cited in 7 scientific papers (total in 7 papers)

Communications

Novel zinc(II)/chitosan-based composite: ultrasound-assisted synthesis, catalytic and antibacterial activity

A. S. Kritchenkov^abc, A. I. Kurachenkov^a, A. R. Egorov^a, N. Z. Yagafarov^ad, E. A. Fortalnova^a, N. N. Lobanov^a, A. P. Dysin^b, A. S. Khomik^a, V. N. Khrustalev^ae

^a Peoples Friendship University of Russia (RUDN University), Moscow, Russian Federation
^b St. Petersburg National Research University of Information Technologies, Mechanics and Optics, St. Petersburg, Russian Federation
^c Institute of Technical Acoustics, National Academy of Sciences of Belarus, Vitebsk, Republic of Belarus
^d N.I. Pirogov Russian National Research Medical University, Moscow, Russian Federation
^e N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Full-text PDF (156 kB) Citations (7)

DOI: https://doi.org/10.1016/j.mencom.2020.09.030

Graphic abstract: Novel zinc(II)/chitosan-based composite: ultrasound-assisted synthesis, catalytic and antibacterial activity

Abstract: Ultrasonic treatment of the reaction between chitosan and aromatic aldehyde, 4-formyl-3-hydroxy-5-hydroxymethyl-1,2-dimethylpyridin-1-ium iodide, resulted in its significant acceleration and increase in degree of derivatization. The CH=N bond of the prepared Schiff base was reduced, and the formed polymeric material was converted into the corresponding zinc(II) composite by treatment with ZnCl₂ and NaOH. The obtained composite is non-toxic, possesses high antibacterial activity and can be employed as the catalyst in the Mannich reaction between benzaldehyde, phenylacetylene and piperidine.

Keywords: chitosan, zinc(II) complexes, antibacterial activity, catalytic activity, Mannich reaction, propargylic amines, pyridoxal.

Document Type: Article

Language: English

*Supplementary materials:*
		Supplementary_data_1.pdf	(1.0 Mb)

Citation: A. S. Kritchenkov, A. I. Kurachenkov, A. R. Egorov, N. Z. Yagafarov, E. A. Fortalnova, N. N. Lobanov, A. P. Dysin, A. S. Khomik, V. N. Khrustalev, “Novel zinc(II)/chitosan-based composite: ultrasound-assisted synthesis, catalytic and antibacterial activity”, Mendeleev Commun., 30:5 (2020), 642–644

Linking options:

https://www.mathnet.ru/eng/mendc1279

https://www.mathnet.ru/eng/mendc/v30/i5/p642

This publication is cited in the following 7 articles:

Domenico Iacopetta, Alessia Catalano, Jessica Ceramella, Annaluisa Mariconda, Assunta D'Amato, Paola Checconi, Stefano Aquaro, Pasquale Longo, Maria Stefania Sinicropi, “Chitosan-Based Schiff Bases (CSBs) and Their Metal Complexes: Promising Antimicrobial Agents”, Molecules, 30:2 (2025), 207
Shazia Hussain, Shiwani Berry, “A review study on green synthesis of chitosan derived schiff bases and their applications”, Carbohydrate Research, 535 (2024), 109002
Jinyu Ouyang, Zhenbiao Li, Jincheng Miao, Yongtao Wang, Langrong Hu, Xiaojuan Wang, “Antibacterial Activity of Carboxymethyl Chitosan Dialdehyde Starch Schiff Base and its Metal Complex”, Starch Stärke, 75:5-6 (2023)
Artem P. Dysin, Anton R. Egorov, Omar Khubiev, Roman Golubev, Anatoly A. Kirichuk, Victor N. Khrustalev, Nikolai N. Lobanov, Vasili V. Rubanik, Alexander G. Tskhovrebov, Andreii S. Kritchenkov, “Novel Highly Efficient Green and Reusable Cu(II)/Chitosan-Based Catalysts for the Sonogashira, Buchwald, Aldol, and Dipolar Cycloaddition Reactions”, Catalysts, 13:1 (2023), 203
M. S. Rubina, A. V. Budnikov, I. V. Elmanovich, I. O. Volkov, A. Yu. Vasil'kov, “Effect of low-pressure radio-frequency air plasma on chitosan films”, Mendeleev Commun., 32:2 (2022), 283–285
A. R. Egorov, N. Z. Yagafarov, A. A. Artemjev, O. Khubiev, B. Medjbour, V. A. Kozyrev, N. D. Sikaona, O. I. Tsvetkova, V. V. Rubanik, V. V. Rubanik, A. V. Kurliuk, T. V. Shakola, N. N. Lobanov, I. S. Kritchenkov, A. G. Tskhovrebov, A. A. Kirichuk, V. N. Khrustalev, A. S. Kritchenkov, “Synthesis and in vitro antifungal activity of selenium-containing chitin derivatives”, Mendeleev Commun., 32:3 (2022), 357–359
A. S. Kritchenkov, M. N. Kurasova, A. A. Godzishevskaya, E. S. Mitrofanova, A. R. Egorov, N. Z. Yagafarov, M. J. Ballesteros Meza, A. G. Tskhovrebov, A. A. Artemjev, E. V. Andrusenko, V. N. Khrustalev, “High antibacterial activity and low toxicity of pyridoxal derivatives of chitosan and their nanoparticles”, Mendeleev Commun., 31:4 (2021), 504–506

Citing articles in Google Scholar: Russian citations, English citations
Related articles in Google Scholar: Russian articles, English articles

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