Abstract:
The reaction of Zn[N(SiMe3)2]2 with N-alkyl-N-[ω- (pentafluorophenylamino)alkyl]-N-[2-(pentafluorophenylamino) ethyl]amines afforded new bicyclic zinc complexes. The complexes initiate ring-opening polymerization of ɛ-caprolactone and trimethylene carbonate to give the corresponding polymers with high molecular weight and satisfactory degree of polymerization.
Citation:
E. A. Kuchuk, B. N. Mankaev, V. A. Serova, K. V. Zaitsev, A. V. Churakov, Yu. F. Oprunenko, G. S. Zaitseva, S. S. Karlov, “New dialkylenetriamine zinc complexes as highly efficient ROP catalysts”, Mendeleev Commun., 30:5 (2020), 596–598
Linking options:
https://www.mathnet.ru/eng/mendc1263
https://www.mathnet.ru/eng/mendc/v30/i5/p596
This publication is cited in the following 8 articles:
Badma N. Mankaev, Valeriia A. Serova, Milana U. Agaeva, Konstantin A. Lyssenko, Artem N. Fakhrutdinov, Andrei V. Churakov, Elena V. Chernikova, Mikhail P. Egorov, Sergey S. Karlov, “Aluminum and titanium complexes bearing 2,6-Bis(2-hydroxyphenyl)pyridines for ring-opening polymerization of lactide, ε-caprolactone and their copolymerization: Effect of a ligand on coordination chemistry and reactivity”, Journal of Organometallic Chemistry, 1005 (2024), 122973
Milana U. Agaeva, Vladislav I. Filippenko, Badma N. Mankaev, Valeriia A. Serova, Konstantin A. Lyssenko, Elena V. Chernikova, Mikhail P. Egorov, Sergey S. Karlov, “Diamidoamine Aluminum Complex as Effective Initiator for Random Copolymerization of Substituted Carbonate with L-Lactide”, Organometallics, 43:20 (2024), 2480
Badma N. Mankaev, Sergey S. Karlov, “Metal Complexes in the Synthesis of Biodegradable Polymers: Achievements and Prospects”, Materials, 16:20 (2023), 6682
M. U. Agaeva, B. N. Mankaev, V. I. Filippenko, K. A. Lysenko, M. P. Egorov, S. S. Karlov, “Zinc Complexes Containing Substituted 1,10-Phenanthrolines as Ligands: Synthesis, Structure and Application as Initiators of ε-Caprolactone, Rac- and L-Lactides Polymerization”, Russ J Gen Chem, 93:S1 (2023), S304
B. N. Mankaev, M. U. Agaeva, M. P. Egorov, S. S. Karlov, “Aluminum complexes based on 1,10-phenanthroline-containing diols: synthesis and application as initiators of polymerization of ε-caprolactone”, Russ Chem Bull, 71:4 (2022), 712
I. E. Nifant'ev, V. V. Bagrov, P. D. Komarov, V. I. Ovchinnikova, P. V. Ivchenko, “Aryloxy 'biometal' complexes as efficient catalysts for the synthesis of poly(butylene adipate terephthalate)”, Mendeleev Commun., 32:3 (2022), 351–353
M. V. Zabalov, B. N. Mankaev, M. P. Egorov, S. S. Karlov, “DFT study of the role of substituents in tin(II) bis(amidoethyl)amine complexes used for ε-caprolactone polymerization”, Mendeleev Commun., 32:4 (2022), 460–463
Ekaterina A. Kuchuk, Marina M. Kireenko, Badma N. Mankaev, Kirill V. Zaitsev, Andrei V. Churakov, Elmira Kh. Lermontova, Lyudmila G. Kuz'mina, Yuri F. Oprunenko, Artem E. Zhirnov, Galina S. Zaitseva, Sergey S. Karlov, “Diamidoamine Aluminum Complexes: Synthesis, Structure, L–Lactide and ϵ‐Caprolactone Polymerization”, ChemistrySelect, 6:38 (2021), 10243
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