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Mendeleev Communications, 2022, Volume 32, Issue 3, Pages 351–353
DOI: https://doi.org/10.1016/j.mencom.2022.05.020
(Mi mendc661)
 

This article is cited in 2 scientific papers (total in 2 papers)

Communications

Aryloxy ‘biometal’ complexes as efficient catalysts for the synthesis of poly(butylene adipate terephthalate)

I. E. Nifant'evab, V. V. Bagrovab, P. D. Komarova, V. I. Ovchinnikovaab, P. V. Ivchenkoab

a A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russian Federation
b Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
Full-text PDF (646 kB) Citations (2)
Abstract: A comparative study of catalytic activity of aryloxy complexes of Mg, Zn and Al in the synthesis of poly(butylene adipate terephthalate) demonstrated the preference of Al-based catalyst containing two bulky substituents in ortho-position of phenol ligand in terms of higher values of PBAT MW and lower yields of cyclic diester side product.
Keywords: aluminum complexes, biodegradable polymers, biometals, esterification, phenates, polycondensation, PBAT, polyesters.
Document Type: Article
Language: English
Supplementary materials:
Supplementary_data_1.pdf (1.4 Mb)


Citation: I. E. Nifant'ev, V. V. Bagrov, P. D. Komarov, V. I. Ovchinnikova, P. V. Ivchenko, “Aryloxy ‘biometal’ complexes as efficient catalysts for the synthesis of poly(butylene adipate terephthalate)”, Mendeleev Commun., 32:3 (2022), 351–353
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  • This publication is cited in the following 2 articles:
    Citing articles in Google Scholar: Russian citations, English citations
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