Abstract:
Heterometallic Coii-Lii compounds with N-heterocyclic carbene 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene (IMes), tri phenylphosphine (Ph3P) and pyridine (py), [Co2Li2(Piv)6(IMes)2] (Piv is the anion of pivalic acid), [Co2Li2(Piv)6(Ph3P)2] and [Co2Li2(Fur)6(py)2] (Fur is the anion of 2-furoic acid), respectively, have been prepared and structurally characterized by X-ray crystallography. Easy-plane magnetic anisotropy in Coii complexes with pseudo-tetrahedral cores CoO3X (X = C, P and N) was revealed by measuring the magnetic properties together with quantum-chemical calculations using the SA-CASSCF/NEVPT2 approach. The field-induced slow magnetic relaxation of the complexes was mainly attributed to the Raman and direct processes.
Keywords:
Ab initio calculations, cobalt(ii), easy-plane magnetic anisotropy, heterometallic carboxylate complexes, N-heterocyclic carbenes, single molecule magnet.
Citation:
D. S. Yambulatov, S. A. Nikolaevskii, M. A. Shmelev, K. A. Babeshkin, D. V. Korchagin, N. N. Efimov, A. S. Goloveshkin, P. A. Petrov, M. A. Kiskin, M. N. Sokolov, I. L. Eremenko, “Heterometallic Coii-Lii carboxylate complexes with N-heterocyclic carbene, triphenylphosphine and pyridine: a comparative study of magnetic properties”, Mendeleev Commun., 31:5 (2021), 624–627
Linking options:
https://www.mathnet.ru/eng/mendc1003
https://www.mathnet.ru/eng/mendc/v31/i5/p624
This publication is cited in the following 26 articles:
Lakshmi Krishnaa Suresh, Pramod Kumar Maniyampara, Nithya Mohan, M. Simi, K. Gopal, M.R. Prathapachandra Kurup, A. Santhy, “Pyrazolyl-derived zinc(II) and cadmium(II) complexes: Synthesis, spectral characterization, single crystal insights, Hirshfeld surface analysis, and in silico DNA interaction studies”, Inorganic Chemistry Communications, 168 (2024), 112811
P. A. Petrov, S. A. Nikolaevskii, E. A. Filippova, N. B. Kompankov, T. S. Sukhikh, M. A. Kiskin, M. N. Sokolov, I. L. Eremenko, “New Polymorph of 1,3-Bis(2,6-di-isopropylphenyl)-4,5-Dichloroimidazole-2-Ylidene and a Cobalt Complex with this Compound”, J Struct Chem, 65:1 (2024), 117
I. K. Rubtsova, P. N. Vasilyev, J. K. Voronina, M. A. Shmelev, N. N. Efimov, S. A. Nikolaevskii, I. L. Eremenko, M. A. Kiskin, “Imidazolium Salts with Heterometallic Complex Anions [Co2Li2(Piv)8]2–: Synthesis, Structures, and Magnetic Properties”, Russ J Coord Chem, 50:7 (2024), 523
S. A. Nikolaevskii, A. A. Starikova, “Quantum Chemical Study of the Structure and Stability of the Adducts of Zn(II) Pivalate with N-Heterocyclic Carbenes”, J Struct Chem, 65:3 (2024), 478
I. K. Rubtsova, P. N. Vasilyev, J. K. Voronina, M. A. Shmelev, N. N. Efimov, S. A. Nikolaevskii, I. L. Eremenko, M. A. Kiskin, “Imidazolium Salts with Heterometallic Complex Anions [Co₂Li₂(Piv)₈]²⁻: Synthesis, Structures, and Magnetic Properties”, Koordinacionnaâ himiâ, 50:11 (2024), 787
I. K. Rubtsova, S. A. Nikolaevskii, I. L. Eremenko, M. A. Kiskin, “Heterometallic Carboxylate Complexes with {Co2Ln} and {Co2Li2} Metal Cores: Synthesis, Structures, and Magnetic Properties”, Russ J Coord Chem, 49:11 (2023), 695
P. A. Petrov, S. A. Nikolaevskii, D. S. Yambulatov, T. S. Sukhikh, A. A. Starikova, M. A. Kiskin, M. N. Sokolov, I. L. Eremenko, “Heteroleptic Cobalt Complexes with Abnormally Coordinated N-Heterocyclic Carbene”, Koordinacionnaâ himiâ, 49:7 (2023), 398
Dmitriy S. Yambulatov, Stanislav A. Nikolaevskii, Anton N. Lukoyanov, Maxim A. Shmelev, Julia K. Voronina, Konstantin A. Babeshkin, Anna K. Matiukhina, Nikolay N. Efimov, Mikhail A. Kiskin, Igor L. Eremenko, “A new cobalt(ii)–lithium(i) carboxylate complex with an N,O-donor mono-iminoacenaphthenone ligand: synthesis, structure and magnetic behavior”, New J. Chem., 47:42 (2023), 19362
D. S. Yambulatov, Yu. K. Voronina, S. A. Nikolaevskii, A. I. Poddel'skii, M. A. Kiskin, I. L. Eremenko, “Tetranuclear Heterometallic Iron(II)–Lithium Carboxylates Stabilized by N-Donor Ligands: Synthesis and Structure”, Koordinacionnaâ himiâ, 49:8 (2023), 466
Evgeniya S. Bazhina, Mikhail A. Kiskin, Konstantin A. Babeshkin, Nikolay N. Efimov, Matvey V. Fedin, Igor L. Eremenko, “Effect of the solvent on the formation of new oxovanadium(IV) complexes with pentafluorobenzoate anions and 1,10-phenanthroline”, Inorganica Chimica Acta, 544 (2023), 121238
P. A. Petrov, S. A. Nikolaevskii, D. S. Yambulatov, T. S. Sukhikh, A. A. Starikova, M. A. Kiskin, M. N. Sokolov, I. L. Eremenko, “Heteroleptic Cobalt Complexes with Abnormally Coordinated N-Heterocyclic Carbene”, Russ J Coord Chem, 49:7 (2023), 407
E. S. Bazhina, M. A. Shmelev, M. A. Kiskin, I. L. Eremenko, “Crystallization Features of LiI-CrIII Coordination Compounds with Cyclobutane-1,1-Dicarboxylic Acid Anions”, J Struct Chem, 64:4 (2023), 550
I. K. Rubtsova, S. A. Nikolaevskii, I. L. Eremenko, M. A. Kiskin, “Heterometallic Carboxylate Complexes with {Co2Ln} and {Co2Li2} Metal Cores: Synthesis, Structures, and Magnetic Properties”, Koordinacionnaâ himiâ, 49:11 (2023), 669
P. A. Petrov, S. A. Nikolaevskii, D. S. Yambulatov, A. A. Starikova, T. S. Sukhikh, M. A. Kiskin, M. N. Sokolov, I. L. Eremenko, “Raznoligandnyi anionnyi kompleks pivalata kobalta(II) s mostikovym trimetilsiloksoligandom: sintez, stroenie i mekhanizm formirovaniya”, Žurnal neorganičeskoj himii, 68:9 (2023), 1255
Mikhail A. Bondarenko, Pavel A. Abramov, Ilya V. Korolkov, Artem S. Bogomyakov, Maxim N. Sokolov, Sergey A. Adonin, “Cu(ii) 3,5-diiodosalicylate complexes: precursor-dependent formation of mono-, di-, tri- and tetranuclear compounds and 1D coordination polymers”, CrystEngComm, 25:1 (2023), 130
P. A. Petrov, S. A. Nikolaevskii, D. S. Yambulatov, A. A. Starikova, T. S. Sukhikh, M. A. Kiskin, M. N. Sokolov, I. L. Eremenko, “Heteroleptic Anionic Cobalt(II) Pivalate Complex with a Bridging Trimethylsiloxy Ligand: Synthesis, Structure, and Formation Mechanism”, Russ. J. Inorg. Chem., 68:9 (2023), 1228
Carlos M. Acosta, Dmitry S. Belov, Andy H. Lamur, ChristiAnna L. Brantley, Xavier Solans-Monfort, Kelly L. Rue, George Christou, Konstantin V. Bukhryakov, “Mononuclear Four-Coordinate Bis-Fluoride Bis-NHC Complexes of Chromium(II), Iron(II), and Cobalt(II)”, Inorg. Chem., 62:44 (2023), 18108
D. S. Yambulatov, J. K. Voronina, S. A. Nikolaevskii, A. I. Poddel'skii, M. A. Kiskin, I. L. Eremenko, “Tetranuclear Heterometallic Iron(II)–Lithium Carboxylates Stabilized by N-Donor Ligands: Synthesis and Structure”, Russ J Coord Chem, 49:8 (2023), 479
S. P. Petrosyants, A. B. Ilyukhin, K. A. Babeshkin, N. N. Efimov, P. S. Koroteev, “New chain polymer [Yb(tpa)(H2O)2Co(CN)6]n · 7n H2O: synthesis, structure, and magnetic characteristics”, Mendeleev Commun., 33:1 (2023), 45–46
T. Z. Sharifullin, A. V. Vasiliev, A. A. Eliseev, A. A. Eliseev, S. Bette, R. E. Dinnebier, R. K. Kremer, P. E. Kazin, “Formation of a single-ion magnet in the lanthanum calcium silicate apatite structure by the cobalt oxide doping”, Mendeleev Commun., 33:6 (2023), 866–868
Contact us: