Аннотация:
Conditions for the highly regioselective reduction of the specified keto groups in the Michael adduct of levoglucosenone and cyclohexanone have been developed. Selective reduction of the keto group in the cyclohexanone moiety was performed under the action of lithium metal in NH3/THF system. Reduction of the keto group in the carbohydrate residue was accomplished microbiologically or by refluxing with NaBH(OAc)3 in benzene.
Ключевые слова:
levoglucosenone, cyclohexanone, Michael adduct, regioselective reduction, ketones.
Образец цитирования:
L. Kh. Faizullina, Yu. S. Galimova, Yu. A. Khalilova, A. R. Tagirov, Sh. M. Salikhov, F. A. Valeev, “Regioselective reduction of keto groups in Michael adducts of levoglucosenone and cyclohexanone”, Mendeleev Commun., 32:5 (2022), 632–633
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc749
https://www.mathnet.ru/rus/mendc/v32/i5/p632
Эта публикация цитируется в следующих 1 статьяx:
L. Kh. Faizullina, A. R. Tagirov, Sh. M. Salikhov, F. A. Valeev, “Ene reaction of Diels–Alder adducts of levoglucosenone and 1,3-dienes with acetaldehyde”, Mendeleev Commun., 33:1 (2023), 9–10
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