Аннотация:
The key enantioselectivity-determining step in Pd-catalyzed asymmetric amination of 2-fluoroallylic substrates was optimized using model reaction of η3-(2-fluorocycloheptenyl)-palladium complexes bearing chiral P,P- and P,N-ligands with various amines. (S)-ButPHOX was found to be the most effective ligand allowing the formation of 2-fluoroallyl amines and anilines with high enantioselectivity.
Образец цитирования:
A. Yu. Bobrova, M. A. Novikov, R. A. Novikov, P. V. Dorovatovskii, A. D. Volodin, A. A. Korlyukov, Yu. V. Tomilov, “Highly enantioselective amination of η3-(2-fluorocycloheptenyl)palladium complexes bearing chiral P,P- and P,N-ligands”, Mendeleev Commun., 32:5 (2022), 619–621
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc744
https://www.mathnet.ru/rus/mendc/v32/i5/p619
Эта публикация цитируется в следующих 3 статьяx:
M. A. Novikov, A. Yu. Bobrova, A. A. Servetnik, E. I. Chernoburova, I. V. Zavarzin, Yu. V. Tomilov, “(XantPhos)AgBr as a cheap and readily available catalyst for the bromofluorocyclopropanation of electron-rich alkenes”, Mendeleev Commun., 34:5 (2024), 698–700
M. M. Efremova, N. V. Rostovskii, “Symposium on the Chemistry of Alkynes, Allenes, and Small Rings”, Russ J Org Chem, 59:12 (2023), 2015
M. M. Efremova, N. V. Rostovskii, “Symposium on chemistry of alkynes, allenes and small cycles”, Žurnal organičeskoj himii, 59:12 (2023), 1525
Обратная связь: