Аннотация:
One-pot synthesis of cyclopentane-fused 5'-aryl-4- cycloalkylamino-2,2'-bipyridines based on the neat (200 °C) reaction of 3-(4-bromopyridin-2-yl)-1,2,4-triazines with enamines is reported. In the course of the transformation, consecutive aza-Diels–Alder reaction and nucleophilic substitution of bromine atom under the action of the liberating amine occur. The possibility of the solvent- and catalyst-free replacement of 4-positioned bromine atom in 2,2'-bipyridines by amino moieties was demonstrated.
Образец цитирования:
A. P. Krinochkin, E. S. Starnovskaya, M. I. Valieva, D. S. Kopchuk, S. Santra, P. A. Slepukhin, G. V. Zyryanov, A. Majee, O. N. Chupakhin, “One-pot synthesis of cyclopentane-fused 5'-aryl-4-cycloalkylamino-2,2'-bipyridines via the aza-Diels–Alder/SNipso reactions”, Mendeleev Commun., 32:4 (2022), 449–451
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc691
https://www.mathnet.ru/rus/mendc/v32/i4/p449
Эта публикация цитируется в следующих 4 статьяx:
Andrei V. Okhokhonin., Marina I. Stepanova, Anton N. Tsmokaluk, Alena V. Mazur, Maria I. Valieva, Ekaterina S. Starnovskaya, Evgeny B. Gorbunov, Vasiliy S. Gaviko, Alexey P. Krinochkin, Dmitry S. Kopchuk, Grigory V. Zyryanov, Alisa N. Kozitsina, Vladimir L. Rusinov, “Synthesis of (3‐Thienyl)‐Substituted 2,2'‐Bipyridines and Their Application as Activators of Platinum Electrode Catalytic Activity Towards Cholesterol Electrooxidation”, ChemistrySelect, 9:10 (2024)
Alexey P. Krinochkin, Maria I. Valieva, Ekaterina A. Kudryashova, Svetlana S. Potapova, Anastasia P. Potapova, Ramil F. Fatykhov, Igor A. Khalymbadzha, Ainur D. Sharapov, Dmitry S. Kopchuk, Igor S. Kovalev, Victoria E. Petrova, Nikolai V. Krivoshchapov, Grigory V. Zyryanov, “Inverse Electron-Demand Diels–Alder Reaction of Pyrazines with 2,5-Norbornadiene as Acetylene Precursor”, Synthesis, 2024
G. N. Kadikova, E. S. Meshcheryakova, L. M. Khalilov, “[4 + 2]-Cycloaddition of maleic anhydride to substituted cycloheptatrienes for the synthesis of novel 4-oxatetracyclo[5.3.2.02,6.08,10]dodec-11-ene-3,5-diones”, Mendeleev Commun., 33:6 (2023), 847–849
Amanda Rodrigues Pinto Costa, Marcelly Muxfeldt, Fernanda da Costa Santos Boechat, Maria Cecília Bastos Vieira de Souza, Jerson Lima Silva, Marcela Cristina de Moraes, Luciana Pereira Rangel, Tuane Cristine Ramos Gonçalves Vieira, Pedro Netto Batalha, “Aminoquinolones and Their Benzoquinone Dimer Hybrids as Modulators of Prion Protein Conversion”, Molecules, 27:22 (2022), 7935
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