Аннотация:
N-Fluorination and N-chlorination of methyl 2-trifluoromethylaziridine-2-carboxylate occurs predominantly from the more hindered side owing to the fixed orientation of the lone electron pair of the N atom caused by the formation of an intramolecular H-bond.
Тип публикации:
Статья
Язык публикации: английский
Образец цитирования:
V. V. Rozhkov, K. N. Makarov, S. N. Osipov, I. I. Chervin, A. V. Ignatenko, R. G. Kostyanovsky, “Methyl 2-trifluoromethylaziridine-2-carboxylate: stereodirected N-halogenation from the sterically more hindered side”, Mendeleev Commun., 7:6 (1997), 229–230