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Эта публикация цитируется в 15 научных статьях (всего в 15 статьях)
Structure and rearrangements of 7-(1,2,3,4,5,6,7-heptaphenylcycloheptatrienyl) isocyanate, isothiocyanate and isoselenocyanate
G. A. Dushenkoa, I. E. Mikhailova, A. Zschunkeb, G. Reckb, B. Schulzb, V. I. Minkina a Institute of Physical and Organic Chemistry, Southern Federal University, Rostov-on-Don, Russian Federation
b Federal Institute for Materials Research and Testing, Berlin, Germany
Аннотация:
In 7-(1,2,3,4,5,6,7-heptaphenylcycloheptatrienyl) isothiocyanate and isoselenocyanate, migration of isothiocyanate and isoselenocyanate groups along the perimeter of the seven-membered ring occurs via an intramolecular dissociation–recombination mechanism with high free energy barriers (ΔG298≠) of 24.3 and 22.4 kcal mol–1, respectively.
Образец цитирования:
G. A. Dushenko, I. E. Mikhailov, A. Zschunke, G. Reck, B. Schulz, V. I. Minkin, “Structure and rearrangements of 7-(1,2,3,4,5,6,7-heptaphenylcycloheptatrienyl) isocyanate, isothiocyanate and isoselenocyanate”, Mendeleev Commun., 9:6 (1999), 222–225
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc4607 https://www.mathnet.ru/rus/mendc/v9/i6/p222
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Страница аннотации: | 21 | PDF полного текста: | 5 |
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