Аннотация:
A general synthetic access to methoxy analogues of coenzymes Q bearing functional substituents with various chain lengths at the quinone ring was developed using available natural (polymethoxy)(methylenedioxy)allylbenzenes. The Baeyer–Villiger rearrangement of (methylenedioxy)benzaldehydes into phenols followed by facile oxidation to quinones with the methylenedioxy moiety opening was identified as the key step in the synthesis of the target 1,4- and 1,2-polyalkoxyquinones
Образец цитирования:
D. V. Tsyganov, D. V. Demchuk, O. I. Adaeva, L. D. Konyushkin, M. E. Minyaev, V. N. Khrustalev, V. V. Semenov, “Synthesis and X-ray diffraction analysis of coenzyme Q derivatives obtained from natural polyalkoxyallylbenzenes”, Mendeleev Commun., 33:4 (2023), 539–542
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc453
https://www.mathnet.ru/rus/mendc/v33/i4/p539
Эта публикация цитируется в следующих 5 статьяx:
Dmitry V. Demchuk, Olga I. Adaeva, Dmitry V. Tsyganov, Darina I. Nasyrova, Roman A. Dolotov, Еgor А. Muravsky, Alexander E. Varakutin, Alexander V. Samet, Victor V. Semenov, “Synthesis of Methoxy Analogues of Coenzyme Q10 Metabolites from Parsley Seed Extracts via Baeyer–Villiger Rearrangement of Carbonyl-Substituted Polyalkoxybenzenes”, Synthesis, 56:16 (2024), 2549
Alexander E. Varakutin, Egor A. Muravsky, Victor N. Khrustalev, Alexander V. Samet, Victor V. Semenov, “Synthesis of Polyalkoxymethylenedioxy-1,4-naphthoquinones from Parsley Seed
Metabolite”, COC, 28:1 (2024), 40
Summaya Fatima, Ameer Fawad Zahoor, Samreen Gul Khan, Syed Ali Raza Naqvi, Syed Makhdoom Hussain, Usman Nazeer, Asim Mansha, Hamad Ahmad, Aijaz Rasool Chaudhry, Ahmad Irfan, “Baeyer–Villiger oxidation: a promising tool for the synthesis of natural products: a review”, RSC Adv., 14:32 (2024), 23423
D. V. Tsyganov, A. I. Samigullina, V. V. Semenov, “Baeyer–Villiger rearrangement of polyalkoxybenzaldehydes with benzene ring opening”, Mendeleev Commun., 34:3 (2024), 396–397
A. V. Samet, D. V. Tsyganov, V. P. Kislyi, E. I. Tujarov, V. V. Semenov, “Synthesis of a new apiol-derived cyclotriveratrylene analog”, Mendeleev Commun., 33:6 (2023), 774–775
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