Аннотация:
The conditions required for resolving racemates into enantiomers by crystallization involve a deficiency of either the conglomerator or the achiral solubiliser to promote the solubility of the compound to be resolved; in both cases the resolution can also be achieved by internal entrainment, adding a single crystal of the resolvable conglomerate.
Тип публикации:
Статья
Язык публикации: английский
Образец цитирования:
R. G. Kostyanovsky, V. R. Kostyanovsky, G. K. Kadorkina, V. Yu. Torbeev, “Resolution of racemates with achiral reagents”, Mendeleev Commun., 10:3 (2000), 83–84
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc4395
https://www.mathnet.ru/rus/mendc/v10/i3/p83
Эта публикация цитируется в следующих 16 статьяx:
Ebrahim Choobdari, Hossein Fakhraian, Mohammad Hassan Peyrovi, “Anion Effect on the Binary and Ternary Phase Diagrams of Chiral Medetomidine Salts and Conglomerate Crystal Formation”, Chirality, 26:3 (2014), 183
Jan Vávra, Lukáš Severa, Ivana Císařová, Blanka Klepetářová, David Šaman, Dušan Koval, Václav Kašička, Filip Teplý, “Search for Conglomerate in Set of [7]Helquat Salts: Multigram Resolution of Helicene–Viologen Hybrid by Preferential Crystallization”, J. Org. Chem., 78:4 (2013), 1329
E. I. Klabunovskii, “Homochirality and its significance for biosphere and the origin of life theory”, Russ J Org Chem, 48:7 (2012), 881
A. A. Bredikhin, Z. A. Bredikhina, D. V. Zakharychev, “Crystallization of chiral compounds: thermodynamical, structural and practical aspects”, Mendeleev Commun., 22:4 (2012), 171–180
Bernd M. Rode, Daniel Fitz, Thomas Jakschitz, “The First Steps of Chemical Evolution towards the Origin of Life”, Chemistry & Biodiversity, 4:12 (2007), 2674
Qiong Ye, Xi-Sen Wang, Hong Zhao, Ren-Gen Xiong, “Spontaneous resolution of a novel chiral coordination polymer through supramolecular interactions and solvent symmetry breaking”, Tetrahedron: Asymmetry, 16:9 (2005), 1595
Witold K. Rybak, Anna Skarżyńska, “Enantiomeric enrichment of a nonracemic conglomerate of a chiral oxo-rhenium(v) complex”, New J. Chem., 27:12 (2003), 1687
R. G. Kostyanovsky, E. N. Nikolaev, O. N. Kharybin, G. K. Kadorkina, V. R. Kostyanovsky, “Pasteur-like resolution of quasi-racemates in solid and gas phases”, Mendeleev Commun., 13:3 (2003), 97–99
R. G. Kostyanovsky, “Louis Pasteur did it for us especially”, Mendeleev Commun., 13:3 (2003), 85–90
R. G. Kostyanovsky, V. Schurig, O. Trapp, K. A. Lyssenko, B. B. Averkiev, G. K. Kadorkina, A. V. Prosyanik, V. R. Kostyanovsky, “Chiral 1-alkoxyaziridines: resolution, nitrogen inversion, stucture and diastereomeric transformations”, Mendeleev Commun., 12:4 (2002), 137–140
R. G. Kostyanovsky, I. A. Bronzova, K. A. Lyssenko, “Directed synthesis of compounds capable to spontaneous resolution”, Mendeleev Commun., 12:1 (2002), 4–6
R. G. Kostyanovsky, F. A. Lakhvich, P. M. Philipchenko, D. A. Lenev, V. Yu. Torbeev, K. A. Lyssenko, “(±)-trans-1,2-Diaminocyclohexane crystallises as a conglomerate”, Mendeleev Commun., 12:4 (2002), 147–149
R. G. Kostyanovsky, G. K. Kadorkina, K. A. Lyssenko, V. Yu. Torbeev, A. N. Kravchenko, O. V. Lebedev, G. V. Grintselev-Knyazev, V. R. Kostyanovsky, “Chiral drugs via the spontaneous resolution”, Mendeleev Commun., 12:1 (2002), 6–8
Remir G. Kostyanovsky, Vladimir Yu. Torbeev, Konstantin A. Lyssenko, “Spontaneous resolution of chiral cobalt(III) complexes”, Tetrahedron: Asymmetry, 12:19 (2001), 2721
V. Yu. Kotov, Yu. G. Gorbunova, S. A. Kostina, G. K. Kadorkina, V. R. Kostyanovsky, R. G. Kostyanovsky, “Outer-sphere association of hexacyanoferrate and nitrogen betaine anions”, Mendeleev Commun., 11:5 (2001), 181–182
R. G. Kostyanovsky, V. R. Kostyanovsky, G. K. Kadorkina, K. A. Lyssenko, “Wedekind–Fock–Havinga salt Me(Et)N+(All)PhI–·CHCl3 as historically the first object for absolute asymmetric synthesis: spontaneous resolution, structure and absolute configuration”, Mendeleev Commun., 11:1 (2001), 1–5