Аннотация:
The unknown 11,12-threo-stereoisomers of B-type trioxilins, (10R, 11R, 12S)-TrXB3, its (10S)-epimer and their enantiomers were synthesized (as methyl esters) from a common racemic precursor, viz., methyl rac-10-hydroxyeicos-11(E)-ene-5,8,14-triynoate, by Sharpless enantiodirected dihydroxylation of the double bond as the key step.
Тип публикации:
Статья
Язык публикации: английский
Образец цитирования:
M. A. Lapitskaya, L. L. Vasiljeva, P. M. Demin, K. K. Pivnitsky, “Enantiodivergent total synthesis of trioxilins B3 using Sharpless asymmetric olefin dihydroxylation”, Mendeleev Commun., 14:6 (2004), 287–290
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