Аннотация:
Fluoride additive to [(p-cymene)RuCl2]2, a readily available ruthenium catalyst, allows one to achieve milder conditions for the reductive alkylation of aldehydes with ketones using carbon monoxide as a reducing agent. The procedure is suitable for the broad substrate scope, and a probable explanation for the fluoride role was provided.
Образец цитирования:
S. A. Runikhina, A. A. Tsygankov, O. I. Afanasyev, D. A. Chusov, “Reductive α-alkylation of ketones with aldehydes at atmospheric pressure of carbon monoxide: the effect of fluoride activation in ruthenium catalysis”, Mendeleev Commun., 33:1 (2023), 17–20
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc294
https://www.mathnet.ru/rus/mendc/v33/i1/p17
Эта публикация цитируется в следующих 2 статьяx:
Aleksei A. Tsygankov, Andrey S. Kozlov, Saihu Liao, Denis Chusov, “Application of transition metal fluorides in catalysis”, Coordination Chemistry Reviews, 519 (2024), 216114
I. V. Smirnov, O. I. Afanasyev, K. O. Biriukov, M. I. Godovikova, D. A. Chusov, “Mn-catalyzed syngas-assisted reductive Knoevenagel condensation”, Mendeleev Commun., 34:6 (2024), 831–833
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