Аннотация:
Phosphine, generated from red phosphorus in the system KOH–H2O–toluene, reacts with vinyl ethers under radical initiation (AIBN, dioxane, 78–80°C, atmospheric pressure) to give tris(2-organyloxyethyl)phosphines, which are transformed to the corresponding phosphine chalcogenides (in up to 73% isolated yield) via the reactions with air oxygen, elemental sulfur or selenium.
Тип публикации:
Статья
Язык публикации: английский
Образец цитирования:
N. K. Gusarova, S. I. Verkhoturova, T. I. Kazantseva, V. L. Mikhailenko, S. N. Arbuzova, B. A. Trofimov, “Free-radical addition of phosphine to vinyl ethers: atom-economic synthesis of tris(2-organyloxyethyl)phosphines and their derivatives”, Mendeleev Commun., 21:1 (2011), 17–18
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc2850
https://www.mathnet.ru/rus/mendc/v21/i1/p17
Эта публикация цитируется в следующих 10 статьяx:
Jian Sun, Yu-Lin Hong, Xiu-Qin Fang, Chang Wang, Cheng-Mei Liu, “Fluorescent phosphine oxide-containing hyperbranched polyesters: design, synthesis and their application for Fe3+detection”, J. Mater. Chem. C, 11:5 (2023), 1927
Akbope K. Borangazieva, Yerzhan A. Boleubayev, Zhuldyz U. Ibraimova, Sholpan S. Itkulova, Gulshara S. Polimbetova, “Catalytic Oxidation of Phosphine by Aqueous Copper–Ammonia Complexes”, Catalysts, 13:2 (2023), 271
Xiang-Qiang Pan, Jian-Ping Zou, Wen-Bin Yi, Wei Zhang, “Recent advances in sulfur- and phosphorous-centered radical reactions for the formation of S–C and P–C bonds”, Tetrahedron, 71:40 (2015), 7481
Toshiaki Murai, Patai's Chemistry of Functional Groups, 2014, 1
G. S. Polimbetova, A. K. Borangazieva, Zh. U. Ibraimova, E. E. Ergozhin, B. A. Mukhitdinova, “Oxidative hydroxylation of phosphine in aqueous alcohol solutions of p-benzoquinone”, Russ. J. Phys. Chem., 88:5 (2014), 764
G. Keglevich, Organophosphorus Chemistry, 2013, 49
D. W. Allen, Organophosphorus Chemistry, 2013, 1
Craig B. Pamplin, Steven J. Rettig, Brian O. Patrick, Brian R. James, “Reactivity of the bridged-sulfide complex Pd2Cl2(μ-S)(μ-dmpm)2toward electrophiles”, Dalton Trans., 41:7 (2012), 1991
Dmitry V. Moiseev, Brian R. James, Thomas Q. Hu, “Characterization of Secondary and Primary (Hydroxymethyl)Phosphines and Their Oxidation Products: Synergism in Pulp-Bleaching”, Phosphorus, Sulfur, and Silicon and the Related Elements, 187:4 (2012), 433
N. K. Gusarova, S. I. Verkhoturova, S. N. Arbuzova, T. I. Kazantseva, B. A. Trofimov, “Nucleophilic addition of phosphine to 1-vinylimidazole”, Russ J Gen Chem, 81:12 (2011), 2522
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