Аннотация:
Palladium-catalyzed potassium carbonate-assisted reaction between diethyl malonate and allyl acetate in the presence of 1,3-dialkyl-imidazolium ionic liquids (ILs) as solvents or phase transfer catalysts affords major monoallylation product, whereas in the presence of 1,2,3-trialkylimidazolium or quaternary ammonium/phosphonium ILs diallylation product is preferably formed. These procedures are extended to some other CH-acids and allylic acetates.
Тип публикации:
Статья
Язык публикации: английский
Образец цитирования:
A. A. Vasil'ev, S. G. Zlotin, “Palladium-catalyzed allylation of malonic acid derivatives in heterogeneous systems containing ionic liquids”, Mendeleev Commun., 24:1 (2014), 23–25
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc2460
https://www.mathnet.ru/rus/mendc/v24/i1/p23
Эта публикация цитируется в следующих 6 статьяx:
A. A. Vasil´ev, I. M. Aladzheva, O. V. Bykhovskaya, “Phase-transfer Tsuji—Trost allylation of CH-acids with the assistance of palladium complexes with bidentate PIII—N—PIII ligands”, Russ Chem Bull, 66:4 (2017), 661
S. V. Savilov, A. O. Artemova, A. S. Ivanov, Z. Shen, S. M. Aldoshin, V. V. Lunin, “Stability of a high-voltage ionic liquid with a substituted piperidinium cation and a TFSI anion, promising for electrochemical applications”, Mendeleev Commun., 26:3 (2016), 240–242
Antonio Monopoli, Pietro Cotugno, Carlo Giorgio Zambonin, Francesco Ciminale, Angelo Nacci, “Highly selective palladium–benzothiazole carbene-catalyzed allylation of active methylene compounds under neutral conditions”, Beilstein J. Org. Chem., 11 (2015), 994
M. A. Epishina, A. S. Kulikov, N. V. Ignat'ev, M. Schulte, N. N. Makhova, “Nucleophilic aromatic cine-substitution of hydrogen: the ionic liquid-promoted von Richter reaction”, Mendeleev Commun., 25:1 (2015), 41–43
Andrei A. Vasil'ev, Sergei G. Zlotin, “ChemInform Abstract: Palladium‐Catalyzed Allylation of Malonic Acid Derivatives in Heterogeneous Systems Containing Ionic Liquids.”, ChemInform, 45:30 (2014)
T. A. Peganova, A. M. Kalsin, N. A. Ustynyuk, A. A. Vasil'ev, “Palladium(II) aminoiminophosphoranate complexes as cross-coupling catalysts”, Russ Chem Bull, 63:10 (2014), 2305
Обратная связь: