Аннотация:
A method for preparation of S-difluoromethyl dithiocarbamates has been developed, which involves the treatment of secondary amines with carbon disulfide in methanol followed by S-difluoromethylation of the intermediate dithiocarbamate anion with difluorocarbene generated from (bromodifluoromethyl)trimethylsilane.
Образец цитирования:
V. O. Smirnov, A. S. Maslov, M. I. Struchkova, D. E. Arkhipov, A. D. Dilman, “Synthesis of S-difluoromethyl dithiocarbamates”, Mendeleev Commun., 25:6 (2015), 452–453
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc2442
https://www.mathnet.ru/rus/mendc/v25/i6/p452
Эта публикация цитируется в следующих 7 статьяx:
Jagadeesh Krishnan, Kaja Sahib, Keerthana G. Nair, Arshad Jouhar T, Rony Rajan Paul, “Advances in the Synthetic Utility of Difluorocarbene Generated from TMSCF3 (Ruppert‐Prakash Reagent) and Its Derivatives”, The Chemical Record, 2025
Zhi Tu, Jinsheng Yu, Jian Zhou, “Synthesis of (Bromodifluoromethyl)trimethylsilane and Its Applications in Organic Synthesis”, Chinese Journal of Organic Chemistry, 43:10 (2023), 3491
Xiu-Ping Chen, Jie Han, Yin-Jie Hu, Yun-Fang Li, Xiang-Cong Wang, Jian-Xiong Ran, Zhong-Hua Wang, Fan-Hong Wu, “Study on the mild, rapid and selective difluorocarbene-mediated triclassification of iododifluoroacetophenone with secondary amines and tree model for product classification”, Tetrahedron, 78 (2021), 131762
Xanath Ispizua-Rodriguez, Colby Barrett, Vinayak Krishamurti, G.K. Surya Prakash, The Curious World of Fluorinated Molecules, 2021, 117
Artem A. Zemtsov, Sergey S. Lunkov, Vitalij V. Levin, Alexander D. Dilman, “Synthesis of Trifluoromethylated Dithiocarbamates via Photocatalyzed Substitution Reaction: Pentafluoropyridine as Activating Reagent”, Eur J Org Chem, 2021:6 (2021), 1007
V. V. Levin, M. I. Struchkova, A. D. Dilman, “Coupling of N-acyliminium chlorides with gem-difluorinated organozinc reagents”, Mendeleev Commun., 27:2 (2017), 139–140
Alexey L. Trifonov, Artem A. Zemtsov, Vitalij V. Levin, Marina I. Struchkova, Alexander D. Dilman, “Nucleophilic Difluoromethylation Using (Bromodifluoromethyl)trimethylsilane”, Org. Lett., 18:14 (2016), 3458
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