Аннотация:
A straightforward and convenient synthesis of new fluorescent 5-aryl-2,2’-bipyridines with the extended conjugation system involves the ‘1,2,4-triazine’ methodology followed by Pd- catalyzed cross-coupling or Wittig reactions using 5-(4-bromo- phenyl)- or 5-(4-bromomethylphenyl)-2,2’-bipyridines as the starting materials. For these compounds, a pronounced bathochromic shift was observed in both absorption and emission spectra compared to previously reported 5-phenyl- 2,2’-bipyridine. For the one of the products, adsorption and fluorescent titrations were fulfilled, fluorescent response on the addition of metal cations was examined.
Образец цитирования:
O. V. Shabunina, D. Yu. Kapustina, A. P. Krinochkin, G. A. Kim, D. S. Kopchuk, G. V. Zyryanov, F. Li, O. N. Chupakhin, “π-Extended fluorophores based on 5-aryl-2,2’-bipyridines: synthesis and photophysical studies”, Mendeleev Commun., 27:6 (2017), 602–604
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc2073
https://www.mathnet.ru/rus/mendc/v27/i6/p602
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