Аннотация:ansa-Complex O[SiMe2(η5-C5H4)]2ZrCl2 upon reduction with LiAlH4 in contrast to zirconocene dichloride forms a dia-magnetic ZrIII complex with the dimeric molecular structure proved by X-ray analysis. This complex after activation by MeAlO initiates oligomerization of α-olefins.
Образец цитирования:
I. E. Nifant'ev, A. A. Vinogradov, A. A. Vinogradov, A. V. Churakov, P. V. Ivchenko, “Synthesis of zirconium(III) complex by reduction of O[SiMe2(η5-C5H4)]2ZrCl2 and its selectivity in catalytic dimerization of hex-1-ene”, Mendeleev Commun., 28:5 (2018), 467–469