Аннотация:
Solid phase thermolysis of pivalate complex [Fe3O(Piv)6(HPiv)3]Piv generates the [Fe3O(Piv)6]+ complex cation due to a deficiency of ligands in the coordination sphere of the metal ions. Crystallization of [Fe3O(Piv)6]+ from THF–EtOH leads to the heteroleptic complex [Fe3O(Piv)6(THF)(EtOH)(OH)] · 0.5 THF · 0.5 H2O in 69% yield, while the reaction of [Fe3O(Piv)6]+ with AgNO3 in toluene results in the complex [Fe4Ag4O2(Piv)12] · 2 PhMe with a rare combination of FeIII and AgI atoms. Crystal structures of the two new complexes have been established.
Образец цитирования:
I. A. Lutsenko, M. A. Kiskin, D. E. Baravikov, Yu. V. Nelyubina, P. V. Primakov, I. L. Eremenko, “Chemical design of heterometallic carboxylate structures with Fe3+ and Ag+ ions as a rational synthetic approach”, Mendeleev Commun., 31:5 (2021), 628–630
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc1004
https://www.mathnet.ru/rus/mendc/v31/i5/p628
Эта публикация цитируется в следующих 3 статьяx:
Lorenzo Marchi, Stefano Carlino, Carlo Castellano, Francesco Demartin, Alessandra Forni, Anna M. Ferretti, Alessandro Ponti, Alessandro Pasini, Luca Rigamonti, “Substituent-Guided Cluster Nuclearity for Tetranuclear Iron(III) Compounds with Flat {Fe4(μ3-O)2} Butterfly Core”, IJMS, 24:6 (2023), 5808
I. A. Lutsenko, M. A. Kiskin, Ya. A. Tigai, E. V. Volchkova, V. K. Imshennik, S. V. Novichikhin, I. L. Eremenko, “Nontrivial Chemical Assembly of a Molecular Complex with Fe3+ and Li+ Cations”, Russ J Coord Chem, 48:11 (2022), 760
D. A. Zherebtsov, V. V. Sharutin, M. A. Polozov, S. A. Naifert, K. Radzhakumar, S. A. Adonin, A. A. Osipov, A. I. Lutsenko, “2,4,6-TRIIODIDE-3-AMINOBENZOATE NICKEL COMPLEXES: SYNTHESIS, STRUCTURE AND NONCOVALENT INTERACTIONS IN THE SOLID STATE”, J Struct Chem, 63:11 (2022), 1850
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