Аннотация:
A novel, eco-friendly and low temperature synthesis of tin (II) monosulfide colloid particles is described. Chemical bath deposition was successfully applied for the deposition of polynanocrystalline SnS from acidic aqueous solutions. The characterization of the prepared samples was accomplished through elemental analysis, scanning electron microscopy, X-ray powder diffraction, and optical spectroscopy. The composition of tin (II) monosulfide colloids assembled of nanoparticles was found to be Sn-rich. Several simple scenarios for Sn surplus within SnS lattice (S-vacancies at S-sublattice, Sn-atoms intercalated between SnS layers and Sn-doping of S-sites) have been analyzed by means of quantum chemical calculations. The potential application of the Sn$_{1+ x}$ S colloid particles in solar cells as absorber material and as photocatalyst was demonstrated by measuring the optical properties.
Ключевые слова:
tin (II) sulfide, chemical bath deposition, optical band gap, Sn-rich.
This work was performed in accordance with the scientific and research plans and state assignment of the ISSC UB RAS (theme AAAA-A19-119031890025-9) and by the Government of the Russian Federation (program 211, project No 02.A03.21.0006).
Поступила в редакцию: 18.09.2020
Реферативные базы данных:
Тип публикации:
Статья
Язык публикации: английский
Образец цитирования:
N. S. Kozhevnikova, L. N. Maskaeva, E. E. Lekomtseva, L. A. Pasechnik, A. Yu. Chufarov, O. A. Lipina, A. N. Enyashin, V. F. Markov, “A facile low-temperature deposition of Sn-rich tin (II) monosulfide colloid particles”, Наносистемы: физика, химия, математика, 11:5 (2020), 529–536
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\paper A facile low-temperature deposition of Sn-rich tin (II) monosulfide colloid particles
\jour Наносистемы: физика, химия, математика
\yr 2020
\vol 11
\issue 5
\pages 529--536
\mathnet{http://mi.mathnet.ru/nano554}
\crossref{https://doi.org/10.17586/2220-8054-2020-11-5-529-536}
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https://www.mathnet.ru/rus/nano554
https://www.mathnet.ru/rus/nano/v11/i5/p529
Эта публикация цитируется в следующих 2 статьяx:
N. S. Kozhevnikova, L. N. Maskaeva, A. N. Enyashin, O. A. Lipina, A. P. Tyutyunnnik, I. O. Selyanin, I. V. Baklanova, M. V. Kuznetsov, V. F. Markov, “Low-Temperature One-Pot Synthesis of Tin(II) Sulfide Nanocrystalline Thin Films”, Russ. J. Inorg. Chem., 2024
N. S. Kozhevnikova, L. N. Maskaeva, A. N. Enyashin, O. A. Lipina, A. P. Tyutyunnik, I. O. Selyanin, I. V. Baklanova, M. V. Kuznetsov, V. F. Markov, “Low-temperature one-pot synthesis of tin(II) sulfide nanocrystalline thin films”, Žurnal neorganičeskoj himii, 69:1 (2024), 3
Цитирование в формате AMSBIB
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