Аннотация:
The phosphatetrasilatricyclo[2.1.0.02,5]pentane cage compound was synthesized by the reaction of the tetrasilacyclobutadiene dianion dipotassium salt precursor with PCl3. The structure, bonding nature, and mechanism of formation of the title compound were studied both experimentally (NMR, X-ray) and computationally (DFT).
Образец цитирования:
V. Ya. Lee, T. Meguro, O. A. Gapurenko, R. M. Minyaev, V. I. Minkin, H. Gornitzka, A. Sekiguchi, “Phosphatetrasilatricyclo[2.1.0.02,5]pentane”, Mendeleev Commun., 32:1 (2022), 33–34
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc561
https://www.mathnet.ru/rus/mendc/v32/i1/p33
Эта публикация цитируется в следующих 2 статьяx:
Vladimir Ya. Lee, Olga A. Gapurenko, “Heavy Tetrel Clusters Based on the Bicyclobutane Framework: Bicyclo[1.1.0]butanes, [1.1.1]Propellanes, and Tricyclo[2.1.0.02,5]pentanes”, Chemistry — An Asian Journal, 19:1 (2024)
Vladimir Ya. Lee, Olga A. Gapurenko, “Pyramidanes: newcomers to the anti-van't Hoff–Le Bel family”, Chem. Commun., 59:67 (2023), 10067