Эта публикация цитируется в 26 научных статьях (всего в 26 статьях)
Direct time-resolved study of the kinetics of the gas-phase reaction of germylene with triethylgermane: a negative activation energy for the Ge–H insertion process
Аннотация:
Gas-phase rate constants, obtained from 292–557 K, yield an activation energy of –10.6±1.1 kJ mol–1 for the insertion reaction of GeH2 into a Ge–H bond (of triethylgermane); these results indicate the likely involvement of an intermediate complex.
Тип публикации:
Статья
Язык публикации: английский
Образец цитирования:
R. Becerra, S. E. Boganov, M. P. Egorov, O. M. Nefedov, R. Walsh, “Direct time-resolved study of the kinetics of the gas-phase reaction of germylene with triethylgermane: a negative activation energy for the Ge–H insertion process”, Mendeleev Commun., 7:3 (1997), 87–88
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc4796
https://www.mathnet.ru/rus/mendc/v7/i3/p87
Эта публикация цитируется в следующих 26 статьяx:
William J. Leigh, Organogermanium Compounds, 2023, 745
Rosa Becerra, J. Pat Cannady, Robin Walsh, “Time‐resolved, Gas‐phase Kinetic and Quantum Chemical Studies of the Reaction of Germylene with Hydrogen Chloride”, ChemPhysChem, 24:10 (2023)
Ruchika Agnihotri, Charlie Oommen, “Kinetics and Mechanism of Thermal and Catalytic Decomposition of Hydroxylammonium Nitrate (HAN) Monopropellant”, Propellants Explo Pyrotec, 46:2 (2021), 286
Nastaran Abedini, Mohammad Z. Kassaee, “A theoretical investigation into novel germylenes: effects of nitrogen substitution on stability and multiplicity”, J Mol Model, 26:11 (2020)
Rosa Becerra, Robin Walsh, “Thermochemistry of germanium and organogermanium compounds”, Phys. Chem. Chem. Phys., 21:3 (2019), 988
Ming-Der Su, “Excited-State Photolytic Mechanism of Cyclopentene Containing a Group 14 Element: An MP2-CAS//CASSCF Study”, J. Phys. Chem. A, 119:32 (2015), 8611
Rosa Becerra, J. Pat Cannady, Robin Walsh, “Reaction of Germylene with Sulfur Dioxide: Gas-Phase Kinetic and Theoretical Studies”, Organometallics, 33:22 (2014), 6493
Ashwini Bundhun, Paul Blowers, Ponnadurai Ramasami, Henry F. Schaefer III, “Quantum Mechanical Modeling for the GeX2/GeHX + GeH4 Reactions (X = H, F, Cl, and Br)”, J. Phys. Chem. A, 114:12 (2010), 4210
Rosa Becerra, Robin Walsh, “Time-resolved gas-phase kinetic study of the germylene addition reaction, GeH2 + C2D2”, Phys. Chem. Chem. Phys., 12:12 (2010), 2923
José M. Riveros, Keiko Takashima, Patai's Chemistry of Functional Groups, 2009
Rosa Becerra, Robin Walsh, “Time-resolved gas-phase kinetic study of the germylene addition reaction, GeH2 + CH3CCCH3”, Phys. Chem. Chem. Phys., 11:18 (2009), 3539
Gerhard F. Swiegers, Mechanical Catalysis, 2008, 55
Rosa Becerra, Sergey E. Boganov, Mikhail P. Egorov, Irina V. Krylova, Oleg M. Nefedov, Robin Walsh, “Direct Time-Resolved Study of the Gas-Phase Reactions of Germylene with Ethyl- and Diethylgermane: Absolute Rate Constants, Temperature Dependences, and Mechanism”, J. Phys. Chem. A, 111:8 (2007), 1434
Rosa Becerra, Sergey E. Boganov, Mikhail P. Egorov, Valery I. Faustov, Irina V. Krylova, Oleg M. Nefedov, Vladimir M. Promyslov, Robin Walsh, “A comparison of the reactivity of germylene and dimethylgermylene with some methylgermanes. Direct kinetic and quantum chemical studies”, Phys. Chem. Chem. Phys., 9:31 (2007), 4395
William J. Leigh, Farahnaz Lollmahomed, Cameron R. Harrington, “Time-Resolved Spectroscopic Studies of the Reactivities of Dimethylgermylene and Tetramethyldigermene in Solution”, Organometallics, 25:8 (2006), 2055
S. E. Boganov, M. P. Egorov, V. I. Faustov, I. V. Krylov, O. M. Nefedov, R. Becerra, R. Walsh, “Gas phase kinetic and theoretical studies of reactions of germylenes and dimethylstannylene”, Russ Chem Bull, 54:3 (2005), 483
William J. Leigh, Cameron R. Harrington, “Di- and Trivalent Organogermanium Reactive Intermediates. Kinetics and Mechanisms of Some Reactions of Diphenylgermylene and Tetraphenyldigermene in Solution”, J. Am. Chem. Soc., 127:14 (2005), 5084
Rosa Becerra, Sergey E. Boganov, Mikhail P. Egorov, Valery I. Faustov, Irina V. Krylova, Oleg M. Nefedov, Vladimir M. Promyslov, Robin Walsh, “An investigation of the germylene addition reaction, GeH2 + C2H2: Time-resolved gas-phase kinetic studies and quantum chemical calculations of the reaction energy surface”, Phys. Chem. Chem. Phys., 6:13 (2004), 3370
Rosa Becerra, J. Pat Cannady, Robin Walsh, “Investigation of the Prototype Silylene Reaction, SiH2 + H2O (and D2O): Time-Resolved Gas-Phase Kinetic Studies, Isotope Effects, RRKM Calculations, and Quantum Chemical Calculations of the Reaction Energy Surface”, J. Phys. Chem. A, 107:50 (2003), 11049
Rosa Becerra, Sergey E. Boganov, Mikhail P. Egorov, Valery I. Faustov, Vladimir M. Promyslov, Oleg M. Nefedov, Robin Walsh, “An investigation of the prototype germylene addition reaction, GeH2 + C2H4: Time-resolved gas-phase kinetic studies and quantum chemical calculations of the reaction energy surface”, Phys. Chem. Chem. Phys., 4:20 (2002), 5079
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