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Аннотация: 1,2-Dimethyl-3-R-diaziridine (R = Bu^t) has been synthesized for the first time; as revealed by NMR the population of its 1,2-cis-form was shown to increase in polar solvents [1,2-cis/1,2-trans = 2 (D₂O), 0.5 (CDCl₃), 0.03 (C₆D₆); for 1,2-trans →1,2-cis in C₆D₆ at 32 °C ΔG^# = 25 kcal mol⁻¹] whereas solely the 1,2-trans-form was detected in diaziridines when R = Me, Et, Prⁱ, Ph.

Эта публикация цитируется в следующих 12 статьяx:

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Kerstin Zawatzky, Matthias Kamuf, Oliver Trapp, “Chiral 1,2‐Dialkenyl Diaziridines: Synthesis, Enantioselective Separation, and Nitrogen Inversion Barriers”, Chirality, 27:2 (2015), 156
Alexander W. Beebe, Emma F. Dohmeier, Gustavo Moura-Letts, “Diastereoselective synthesis of substituted diaziridines from simple ketones and aldehydes”, Chem. Commun., 51:70 (2015), 13511
Matthias Kamuf, Oliver Trapp, “Stereodynamics of Small 1,2‐Dialkyldiaziridines”, Chirality, 25:4 (2013), 224
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