Аннотация:
The carbonylation of C6–C10n-alkanes with CO in the presence of CBr4·2AlBr3 at –40 °C and 1 atm CO leads to the products of non-destructive carbonylation, i.e., the esters of tertiary carboxylic acids, R1C(Me)2COOR and R2(Et)C(Me)COOR, after the workup of reaction mixtures with ROH.
Тип публикации:
Статья
Язык публикации: английский
Образец цитирования:
I. S. Akhrem, L. V. Afanas'eva, S. V. Vitt, P. V. Petrovskii, “First examples of the selective carbonylation of C6–C10 linear alkanes to tertiary carbonyl-containing compounds”, Mendeleev Commun., 12:5 (2002), 180–182