Аннотация:
The replacement of naphthalene ligand in the ruthenium complex [CpRu(C10H8)]+ by halide anions in the presence of 1,5-cyclooctadiene (cod) or norbornadiene (nbd) gives important synthetic precursors CpRu(cod)X and CpRu(nbd)X (X=Cl, Br, I) in 60–90% yield; the structure of CpRu(nbd)Br was determined by X-ray diffraction.
Образец цитирования:
D. S. Perekalin, E. E. Karslyan, A. O. Borissova, A. R. Kudinov, “Convenient synthesis of the ruthenium complexes CpRu(diene)X (X=Cl, Br, I) by naphthalene substitution in [CpRu(C10H8)]+”, Mendeleev Commun., 21:2 (2011), 82–83
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc2872
https://www.mathnet.ru/rus/mendc/v21/i2/p82
Эта публикация цитируется в следующих 13 статьяx:
Lukas Hintermann, Encyclopedia of Reagents for Organic Synthesis, 2022, 1
Nikita V. Shvydkiy, Dmitry S. Perekalin, “Reactions of arene replacement in transition metal complexes”, Coordination Chemistry Reviews, 411 (2020), 213238
Eva Bocekova‐Gajdošíkova, Bugra Epik, Jingyu Chou, Katsuhiro Akiyama, Nobuaki Fukui, Laure Guénée, E. Peter Kündig, “Microwave‐Assisted Synthesis and Transformations of Cationic CpRu(II)(naphthalene) and CpRu(II)(naphthoquinone) Complexes”, Helvetica Chimica Acta, 102:5 (2019)
Jeremy Stone, David Jago, Alexandre Sobolev, Mark Spackman, George Koutsantonis, “Facile Synthesis of Pentamethylcyclopentadienyl Ruthenium Half-Sandwich Complexes by Naphthalene Displacement”, Aust. J. Chem., 71:4 (2018), 289
Frederick P. Malan, Afsar Ali, Eric Singleton, Reinout Meijboom, “The dominant steric effect in the synthesis of ammine hydrido- and chlorido-Ru(II)- N , N -dimethylhydrazine and mixed alkyl–aryl phosphine complexes: Novel methyldiazene reduction intermediates”, Inorganica Chimica Acta, 437 (2015), 133
D. S. Perekalin, N. V. Shvydkiy, Yu. V. Nelyubina, A. R. Kudinov, “Synthesis of the half-sandwich ruthenium complexes [Cp*RuL3]+ via naphthalene replacement in [Cp*Ru(C10H8)]+”, Mendeleev Commun., 25:1 (2015), 29–31
Dmitry S. Perekalin, Alexander R. Kudinov, “Cyclopentadienyl ruthenium complexes with naphthalene and other polycyclic aromatic ligands”, Coordination Chemistry Reviews, 276 (2014), 153
Dmitry S. Perekalin, Alexander P. Molotkov, Yulia V. Nelyubina, Natalia Yu. Anisimova, Alexander R. Kudinov, “Synthesis of amino acid esters of the ruthenium naphthalene complex [(C5Me4CH2OH)Ru(C10H8)]+”, Inorganica Chimica Acta, 409 (2014), 390
Jason M. Lynam, Lucy M. Milner, Neetisha S. Mistry, John M. Slattery, Sally R. Warrington, Adrian C. Whitwood, “[Ru(η5-C5H5)(η6-C10H8)]PF6as a catalyst precursor for the one-pot direct C–H alkenylation of nitrogen heterocycles”, Dalton Trans., 43:11 (2014), 4565
Dmitry S. Perekalin, Evgeniya A. Trifonova, Valentin V. Novikov, Yulia V. Nelyubina, Alexander R. Kudinov, “Reactions of the cyclopentadienyl ruthenium complexes (C5R5)Ru(cod)Cl and [(C5R5)Ru(MeCN)3]+ (R = H, Me) with phenylacetylene and acetic acid: Unexpected difference in reactivity of CpRu and Cp*Ru complexes”, Journal of Organometallic Chemistry, 737 (2013), 21
Dmitry S. Perekalin, Eduard E. Karslyan, Evgeniya A. Trifonova, Andrew I. Konovalov, Natalia L. Loskutova, Yulia V. Nelyubina, Alexander R. Kudinov, “Synthesis of Ruthenium Half‐Sandwich Complexes by Naphthalene Replacement in [CpRu(C10H8)]+”, Eur J Inorg Chem, 2013:4 (2013), 481
Dmitry S. Perekalin, Eduard E. Karslyan, Pavel V. Petrovskii, Alexandra O. Borissova, Konstantin A. Lyssenko, Alexander R. Kudinov, “Arene Exchange in the Ruthenium–Naphthalene Complex [CpRu(C10H8)]+”, Eur J Inorg Chem, 2012:9 (2012), 1485
D. S. Perekalin, E. A. Trifonova, P. V. Petrovskii, A. R. Kudinov, “Cyclotrimerization of alkynes catalyzed by the naphthalene ruthenium complex [CpRu(C10H8)]+”, Russ Chem Bull, 60:10 (2011), 2110
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