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Reaction of 3,3’ -bis(2-phenyl-5,5-dimethyl-4-oxopyrrolinylidene) 1,1’ -Dioxide with the Methoxide Anion
I. A. Khalfina, N. V. Vasilieva, I. G. Irtegova, V. A. Reznikov, L. A. Shundrin
N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation
Аннотация:
The title reaction in methanol includes the addition of MeO– to the carbonyl group of a pyrrolinone ring followed by ring opening, and the one-electron oxidation of the formed anion results in the formation of a stable nitroxide, as found by cyclic voltammetry and EPR spectroscopy.
Ключевые слова:
nitrones, dinitrones, nucleophilic addition, methoxide anion, cyclic voltammetry.
Образец цитирования:
I. A. Khalfina, N. V. Vasilieva, I. G. Irtegova, V. A. Reznikov, L. A. Shundrin, “Reaction of 3,3’ -bis(2-phenyl-5,5-dimethyl-4-oxopyrrolinylidene) 1,1’ -Dioxide with the Methoxide Anion”, Mendeleev Commun., 22:6 (2012), 327–329
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc2838 https://www.mathnet.ru/rus/mendc/v22/i6/p327
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