Аннотация:
The spontaneous reaction of disubstituted malonyl peroxides (MPOs) with methanol affording monopermalonic acid monomethyl esters is fast (minutes) for lower homologues but is sharply decelerated (days) for the higher ones. Spirocyclopropyl-MPO is an exception in which the nucleophilic opening of the spiroactivated cyclopropane ring leads to 2,4-dimethoxy-2-carboxybutanoic acid.
Образец цитирования:
M. A. Lapitskaya, V. A. Vil', L. L. Vasiljeva, E. D. Daeva, A. O. Terent'ev, K. K. Pivnitsky, “Spontaneous reaction of malonyl peroxides with methanol”, Mendeleev Commun., 27:3 (2017), 243–245
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc1955
https://www.mathnet.ru/rus/mendc/v27/i3/p243
Эта публикация цитируется в следующих 3 статьяx:
Y. Barsegyan, V. A. Vil', N. C. O. Tomkinson, A. O. Terent'ev, Knowledge Updates 2022/1, 2022
O. V. Bityukov, V. A. Vil', N. V. Lukashin, A. G. Cherednichenko, G. I. Nikishin, A. O. Terent'ev, “Solvent-free silica gel mediated decarboxylation of C–O coupling products of β-diketones and β-oxo esters with malonyl peroxides”, Mendeleev Commun., 29:1 (2019), 55–56
M. A. Lapitskaya, V. A. Vil', E. D. Daeva, A. O. Terent'ev, K. K. Pivnitsky, “Dimethylmalonoyl peroxide – the neglected lowest homologue: simple synthesis and high reactivity”, Mendeleev Commun., 28:5 (2018), 505–507
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