aDepartment of Organic Chemistry and Technology, Budapest University of Technology and Economics, Budapest, Hungary bSpectroscopic Research Division, Gedeon Richter Plc., Budapest, Hungary
Аннотация:
The reaction of dimethyl (1-aryl-1-hydroxymethyl)phosphonates with 1-chloro-3-phospholene 1-oxides, diphenylphosphinic chloride or diphenyl chloridophosphonate affords the corresponding (1-phosphoryloxymethyl)phosphonates. The products with two different >P(O)– moieties exhibit characteristic δP shifts and 3JP,P couplings in the 31P NMR spectra.
Образец цитирования:
Z. Radai, V. Hodula, N. Z. Kiss, J. Koti, G. T. Keglevich, “Phosphorylation of (1-aryl-1-hydroxymethyl)phosphonates”, Mendeleev Commun., 29:2 (2019), 153–154
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc1453
https://www.mathnet.ru/rus/mendc/v29/i2/p153
Эта публикация цитируется в следующих 13 статьяx:
Zsuzsanna Szalai, Anna Sára Kis, Angéla Takács, László Kőhidai, Konstantin Karaghiosoff, Mátyás Czugler, László Drahos, György Keglevich, “The Synthesis, Crystal Structure, Modification, and Cytotoxic Activity of α-Hydroxy-Alkylphosphonates”, Molecules, 30:2 (2025), 428
Zsuzsanna Szalai, Márton Debrei, Péter Ábrányi-Balogh, Szilvia Bősze, Rita Oláhné Szabó, Konstantin Karaghiosoff, László Drahos, György Keglevich, “Synthesis of Mesylated and Tosylated α-Hydroxy-Benzylphosphonates; Their Reactivity and Cytostatic Activity”, ACS Omega, 9:28 (2024), 31043
Mátyás Milen, Cintia Bese, Csenge Kovács, András Dancsó, György Keglevich, “The Addition of α-Hydroxy-benzylphosphonates to Dialkyl Acetylenedicarboxylates; Catalytic Hydrogenation of the Adducts”, Synthesis, 56:19 (2024), 3074
Zsuzsanna Szalai, Péter Ábrányi-Balogh, György Keglevich, “Unexpected Reaction of Dialkyl α-Hydroxy-benzylphosphonates with Dialkyl Phosphites and a Few Related Reactions”, J. Org. Chem., 2024
Liguang Gan, Tianhao Xu, Qihang Tan, Mengjie Cen, Lingling Wang, Jingwei Zhao, Kuang Liu, Long Liu, Wen-Hao Chen, Li-Biao Han, Jacek E. Nycz, Tieqiao Chen, “Metal-free highly chemo-selective bisphosphorylation and deoxyphosphorylation of carboxylic acids”, Chem. Sci., 14:20 (2023), 5519
R. R. Davletshin, A. N. Sedov, N. V. Davletshina, K. A. Ivshin, A. P. Fedonin, A. R. Osogostok, R. A. Cherkasov, “Catalysis of the Abramov Reaction under Conditions of Microwave Activation”, Russ. J. Phys. Chem., 97:7 (2023), 1402
R. R. Davletshin, A. N. Sedov, N. V. Davletshina, K. A. Ivshin, A. P. Fedonin, A. P. Osogostok, R. A. Cherkasov, “Catalysis of the Abramov Reaction under Conditions of Microwave Activation”, Russian Journal of Physical Chemistry, 97:7 (2023), 960
Konstantin Belov, Valery Brel, Valentina Sobornova, Irina Fedorova, Ilya Khodov, “Conformational Analysis of 1,5-Diaryl-3-Oxo-1,4-Pentadiene Derivatives: A Nuclear Overhauser Effect Spectroscopy Investigation”, IJMS, 24:23 (2023), 16707
Petra R. Varga, Alexandra Belovics, Péter Bagi, Szilárd Tóth, Gergely Szakács, Szilvia Bősze, Rita Szabó, László Drahos, György Keglevich, “Efficient Synthesis of Acylated, Dialkyl α-Hydroxy-Benzylphosphonates and Their Anticancer Activity”, Molecules, 27:7 (2022), 2067
Xin-Yue Zhang, Qi-Wei Li, Hui-Qi Yue, Zi-Qian Wu, Ji Li, Ming Li, Lu Lu, Shang-Dong Yang, Bin Yang, “Bisphosphorylation of anhydrides – convenient access to bisphosphonates with a P–O–C–P motif”, Chem. Commun., 58:46 (2022), 6665
György Keglevich, Nikoletta Harsági, Petra R. Varga, Bianka Huszár, Réka Henyecz, Nóra Z. Kiss, Zoltán Mucsi, Péter Bagi, “Newer developments in the green synthesis of tertiary phosphine oxides, phosphinates, phosphonates and their derivatives”, Phosphorus, Sulfur, and Silicon and the Related Elements, 197:5-6 (2022), 420
Nikoletta Harsági, Zita Rádai, Áron Szigetvári, János Kóti, György Keglevich, “Optimization and a Kinetic Study on the Acidic Hydrolysis of Dialkyl α-Hydroxybenzylphosphonates”, Molecules, 25:17 (2020), 3793
Zita Rádai, Réka Szabó, Áron Szigetvári, Nóra Zsuzsa Kiss, Zoltán Mucsi, György Keglevich, “A Study on the Rearrangement of Dialkyl 1-Aryl-1-hydroxymethylphosphonates to Benzyl Phosphates”, COC, 24:4 (2020), 465